On the electrical capacitance of interfaces exhibiting constant phase element behaviour

ac Impedance of Faradaic reactions involving electrosorbed intermediates—I. Kinetic theory

Behavior of overpotential—deposited species in Faradaic reactions—II. ac Impedance measurements on H2 evolution kinetics at activated and unactivated Pt cathodes

Modeling of uniform CO2 corrosion of mild steel in gas transportation systems: A review

The hydrogen evolution reaction on the low index planes of single-crystal Au electrodes has been studied in HClO4 solutions with the aim of ascertaining the extent of the sensitivity of the reaction rate to the surface crystallographic structure. The use of the hanging meniscus rotating disk technique allowed to carry out all measurements under rotation, thus avoiding blocking effects produced by hydrogen bubbles and accumulation of dissolved hydrogen in the interfacial region during potential excursions into relatively high overpotentials. In contrast with previously published results showing only slight variations in activity with Au crystal face, a pronounced structural sensitivity is reported for the first time. The catalytic activity presents the following sequence Au(111) > Au(100) > Au(110).

Hydrogen Evolution Reaction on Gold Single-Crystal Electrodes in Acid Solutions

https://dspace.library.uu.nl/bitstream/handle/1874/15463/brug_84_kinetics_reduction.pdf?sequence=1

A. Hemelin

Papers

The kinetics of the reduction of protons at polycrystalline and monocrystalline gold electrodes