Infrared spectra of complexes of the thiocyanate and related ions

Linkage isomerism in metal complexes

Metal complexes of sulphur and nitrogen-containing ligands: Complexes of s-benzyldithiocarbazate and a schiff base formed by its condensation with pyridine-2-carboxaldehyde

Recent developments in the coordination chemistry of ambidentate ligands

By using confocal microprobe Raman spectroscopy and a unique electrochemical pretreatment procedure for the Pt surface, we are able to extend the detailed surface Raman studies, for the first time, to bare Pt electrodes in a wide potential region (e.g. −1.0 to +1.4 V vs SCE) and to more general adsorbates such as SCN- and CO having small Raman scattering cross sections. Taking advantage of being capable of observing the adsorbate−metal vibrational bands in the low-frequency region over IR and SFG techniques, the surface Raman spectroscopy has demonstrated the virtues of yielding detailed information on the surface bonding affected by surface coverage, coadsorbate, electrolyte ions, and electrode potential. The potential-dependent Raman spectra of SCN- reveal that the N-bound adsorbate is favored at the more negative potentials. The orientation conversion to the S-bound species occurs in the more positive region, depending on the SCN- concentration. In a solution of 10-5 M NaSCN and 0.1 M NaClO4, a new C−N...

Extending Surface Raman Spectroscopy to Transition Metal Surfaces for Practical Applications. 1. Vibrational Properties of Thiocyanate and Carbon Monoxide Adsorbed on Electrochemically Activated Platinum Surfaces

A. Sabatini

Papers

Infrared Spectra between 100 and 2500 Cm.-1 of Some Complex Metal Cyanates, Thiocyanates, and Selenocyanates