Every few years, a new material with unique properties emerges and fascinates the scientific community, typical recent examples being high-temperature superconductors and carbon nanotubes. Graphene is the latest sensation with unusual properties, such as half-integer quantum Hall effect and ballistic electron transport. This two-dimensional material which is the parent of all graphitic carbon forms is strictly expected to comprise a single layer, but there is considerable interest in investigating two-layer and few-layer graphenes as well. Synthesis and characterization of graphenes pose challenges, but there has been considerable progress in the last year or so. Herein, we present the status of graphene research which includes aspects related to synthesis, characterization, structure, and properties.

Graphene: The New Two-Dimensional Nanomaterial

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.

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Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

Graphene can be viewed as an individual atomic plane extracted from graphite, as unrolled single-walled carbon nanotube or as an extended flat fullerene molecule. In this paper, a facile approach to the synthesis of high quality graphene nanosheets in large scale through electrochemical reduction of exfoliated graphite oxide precursor at cathodic potentials (completely reduced potential: −1.5 V) is reported. This method is green and fast, and will not result in contamination of the reduced material. The electrochemically reduced graphene nanosheets have been carefully characterized by spectroscopic and electrochemical techniques in comparison to the chemically reduced graphene-based product. Particularly, FTIR spectra indicate that a variety of the oxygen-containing functional groups have been thoroughly removed from the graphite oxide plane via electrochemical reduction. The chemically converted materials are not expected to exhibit graphene’s electronic properties because of residual defects. Indeed, th...

A Green Approach to the Synthesis of Graphene Nanosheets

Owing to their extraordinary electrical, chemical, optical, mechanical and structural properties, graphene and its derivatives have stimulated exploding interests in their sensor applications ever since the first isolation of free-standing graphene sheets in year 2004. This article critically and comprehensively reviews the emerging graphene-based electrochemical sensors, electronic sensors, optical sensors, and nanopore sensors for biological or chemical detection. We emphasize on the underlying detection (or signal transduction) mechanisms, the unique roles and advantages of the used graphene materials. Properties and preparations of different graphene materials, their functionalizations are also comparatively discussed in view of sensor development. Finally, the perspective and current challenges of graphene sensors are outlined (312 references).

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Biological and chemical sensors based on graphene materials

Sensing strain of soft materials in small scale has attracted increasing attention. In this work, graphene woven fabrics (GWFs) are explored for highly sensitive sensing. A flexible and wearable strain sensor is assembled by adhering the GWFs on polymer and medical tape composite film. The sensor exhibits the following features: ultra-light, relatively good sensitivity, high reversibility, superior physical robustness, easy fabrication, ease to follow human skin deformation, and so on. Some weak human motions are chosen to test the notable resistance change, including hand clenching, phonation, expression change, blink, breath, and pulse. Because of the distinctive features of high sensitivity and reversible extensibility, the GWFs based piezoresistive sensors have wide potential applications in fields of the displays, robotics, fatigue detection, body monitoring, and so forth.

Abolhassan Vafai

Papers

Applications of single-layered graphene sheets as mass sensors and atomistic dust detectors

Potential application of single-layered graphene sheet as strain sensor

Experimental study on cyclic behavior of trapezoidally corrugated steel shear walls

Application of Endurance Time method in linear seismic analysis

Modeling crack in orthotropic media using a coupled finite element and partition of unity methods