N-silylated benzamidines: versatile building blocks in main group and coordination chemistry

Synthesis, Structures, Bonding, and Ethylene Reactivity of Group 4 Metal Alkyl Complexes Incorporating 8-Quinolinolato Ligands

Polymerization catalysis with transition metal amidinate and related complexes

Titanium(II), -(III), and -(IV) Complexes Supported by Benzamidinate Ligands

Bulky Bis(alkylamidinate) Complexes of Group 4. Syntheses and Characterization of M(CyNC(R‘)NCy)2Cl2 and Zr(CyNC(Me)NCy)2Me2 (R‘= Me, M = Ti, Zr, Hf; R‘ = tBu, M = Zr)

The new compounds [M(η-C5R5){η-R′NC(Ph)NR′}Cl2][where R′= Me3,Si (TMS), and R = H, M = Ti,Zr, Hf or R = Me, M = Ti or Zr], [Zr(η-C5R5){(η-R′NC(Ph)NR′}(CH2Ph)Cl](R = H, Me), and [Zr(η-C5R5){η-R′NC(Ph)NR}(CH2Ph)2](R = H, Me) are described; the compound [Zr(η-C5H5){η-R′C(Ph)R′}Cl2] acts as a cocatalyst for the polymerisation of ethylene and propene.

Alexandrov N. Chernega

Papers

Mono-η-cyclopentadienyl-benzamidinato compounds of titanium, zirconium and hafnium