When a viscous fluid filling the voids in a porous medium is driven forwards by the pressure of another driving fluid, the interface between them is liable to be unstable if the driving fluid is the less viscous of the two. This condition occurs in oil fields. To describe the normal modes of small disturbances from a plane interface and their rate of growth, it is necessary to know, or to assume one knows, the conditions which must be satisfied at the interface. The simplest assumption, that the fluids remain completely separated along a definite interface, leads to formulae which are analogous to known expressions developed by scientists working in the oil industry, and also analogous to expressions representing the instability of accelerated interfaces between fluids of different densities. In the latter case the instability develops into round-ended fingers of less dense fluid penetrating into the more dense one. Experiments in which a viscous fluid confined between closely spaced parallel sheets of glass, a Hele-Shaw cell, is driven out by a less viscous one reveal a similar state. The motion in a Hele-Shaw cell is mathematically analogous to two-dimensional flow in a porous medium.
Analysis which assumes continuity of pressure through the interface shows that a flow is possible in which equally spaced fingers advance steadily. The ratio λ = (width of finger)/(spacing of fingers) appears as the parameter in a singly infinite set of such motions, all of which appear equally possible. Experiments in which various fluids were forced into a narrow Hele-Shaw cell showed that single fingers can be produced, and that unless the flow is very slow λ = (width of finger)/(width of channel) is close to , so that behind the tips of the advancing fingers the widths of the two columns of fluid are equal. When λ = 1/2 the calculated form of the fingers is very close to that which is registered photographically in the Hele-Shaw cell, but at very slow speeds where the measured value of λ increased from 1/2 to the limit 1.0 as the speed decreased to zero, there were considerable differences. Assuming that these might be due to surface tension, experiments were made in which a fluid of small viscosity, air or water, displaced a much more viscous oil. It is to be expected in that case that λ would be a function of μU/T only, where μ is the viscosity, U the speed of advance and T the interfacial tension. This was verified using air as the less viscous fluid penetrating two oils of viscosities 0.30 and 4.5 poises.

The Penetration of a Fluid into a Porous Medium or Hele-Shaw Cell Containing a More Viscous Liquid

A long bubble of a fluid of negligible viscosity is moving steadily in a tube filled with liquid of viscosity μ at small Reynolds number, the interfacial tension being σ. The angle of contact at the wall is zero. Two related problems are treated here.In the first the tube radius r is so small that gravitational effects are negligible, and theory shows that the speed U of the bubble exceeds the average speed of the fluid in the tube by an amount UW, where (This result is in error by no more than 10% provided ). The pressure drop, P, across such a bubble is given by and W is uniquely determined by conditions near the leading meniscus. The interface near the rear meniscus has a wave-like appearance. This provides a partial theory of the indicator bubble commonly used to measure liquid flowrates in capillaries. A similar theory is applicable to the two-dimensional motion round a meniscus between two parallel plates. Experimental results given here for the value of W agree well neither with theory nor with previous experiments by other workers. No explanation is given for the discrepancies.In the second problem the tube is wider, vertical, and sealed at one end. The bubble now moves under the effect of gravity, but it is shown that it will not rise at all if where ρ is the difference in density between the fluids inside and outside the bubble. If accurate to within 10%. Experiments are adduced in support of these results, though there is disagreement with previous work.

The motion of long bubbles in tubes

We review transport characteristics of pressure-driven, multiphase flows through microchannel networks tens of nanometres to several hundred of micrometres wide with emphasis on conditions resulting in enhanced mixing and reduced axial dispersion. Dimensionless scaling parameters useful in characterizing multiphase flows are summarized along with experimental flow visualization techniques. Static and dynamic stability considerations are also included along with methods for stabilizing multiphase flows through surface modifications. Observed gas–liquid and immiscible liquid–liquid flows are summarized in terms of flow regime diagrams and the different flows are related to applications in chemistry and materials synthesis. Means to completely separate multiphase flows on the microscale and guidelines for design of scalable multiphase systems are also discussed.

Multiphase microfluidics: from flow characteristics to chemical and materials synthesis

This critical review discusses the current understanding of the formation, transport, and merging of drops in microfluidics. We focus on the physical ingredients which determine the flow of drops in microchannels and recall classical results of fluid dynamics which help explain the observed behaviour. We begin by introducing the main physical ingredients that differentiate droplet microfluidics from single-phase microfluidics, namely the modifications to the flow and pressure fields that are introduced by the presence of interfacial tension. Then three practical aspects are studied in detail: (i) The formation of drops and the dominant interactions depending on the geometry in which they are formed. (ii) The transport of drops, namely the evaluation of drop velocity, the pressure-velocity relationships, and the flow field induced by the presence of the drop. (iii) The fusion of two drops, including different methods of bridging the liquid film between them which enables their merging.

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Dynamics of microfluidic droplets.

Measurements of the amount of fluid left behind when a viscous liquid is blown from an open-ended tube are described.

Alfred E. Stubbs

Papers

119. Studies in electro-endosmosis. Part VI. The “bubble-tube” method of measurement

291. Studies in electro-endosmosis. Part VII. Some measurements with non-aqueous liquids and high voltages