Lanthanide-based luminescent hybrid materials.

Switches, and Actuators Masahiro Irie,*,† Tuyoshi Fukaminato,‡ Kenji Matsuda, and Seiya Kobatake †Research Center for Smart Molecules, Rikkyo University, Nishi-Ikebukuro 3-34-1, Toshima-ku, Tokyo 171-8501, Japan ‡Research Institute for Electronic Science, Hokkaido University, N20, W10, Kita-ku, Sapporo 001-0020, Japan Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, Sugimoto 3-3-138, Sumiyoshi-ku, Osaka 558-8585, Japan

Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators

Water gelation by small organic molecules.

A theoretical perspective is provided on the glass transition in molecular liquids at thermal equilibrium, on the spatially heterogeneous and aging dynamics of disordered materials, and on the rheology of soft glassy materials. We start with a broad introduction to the field and emphasize its connections with other subjects and its relevance. The important role played by computer simulations in studying and understanding the dynamics of systems close to the glass transition at the molecular level is given. The recent progress on the subject of the spatially heterogeneous dynamics that characterizes structural relaxation in materials with slow dynamics is reviewed. The main theoretical approaches are presented describing the glass transition in supercooled liquids, focusing on theories that have a microscopic, statistical mechanics basis. We describe both successes and failures and critically assess the current status of each of these approaches. The physics of aging dynamics in disordered materials and the rheology of soft glassy materials are then discussed, and recent theoretical progress is described. For each section, an extensive overview is given of the most recent advances, but we also describe in some detail the important open problems that will occupy a central place in this field in the coming years.

Theoretical perspective on the glass transition and amorphous materials

Intermolecular And Surface Forces

We report on an experimental study of the shear-banding phenomenon in the concentrated wormlike micellar system CTAB at 20 wt. % in D2O. Time-resolved velocity profiles are recorded using ultrasonic velocimetry simultaneously to global rheological data. Our results confirm the studies performed previously by Fischer and Callaghan (Phys. Rev. E 64, 011501 2001). Time averaged velocity profiles display an unsheared “nematic gel.” In the range of applied shear rate, the flow field exhibits very fast temporal fluctuations. Suspicions for the presence of three-dimensional flow are evidenced and possible causes for a three-dimensional instability are discussed together with the coupling of wall slip to bulk dynamic.

Evidence for three-dimensional unstable flows in shear-banding wormlike micelles.

Amorphous glassy materials of diverse nature-concentrated emulsions, granular materials, pastes, molecular glasses-display complex flow properties, intermediate between solid and liquid, which are at the root of their use in many applications. A general feature of such systems, well documented yet not really understood, is the strongly nonlinear nature of the flow rule relating stresses and strain rates. Here we use a microfluidic velocimetry technique to characterize the flow of thin layers of concentrated emulsions, confined in gaps of different thicknesses by surfaces of different roughnesses. We find evidence for finite-size effects in the flow behaviour and the absence of an intrinsic local flow rule. In contrast to the classical nonlinearities of the rheological behaviour of amorphous materials, we show that a rather simple non-local flow rule can account for all the velocity profiles. This non-locality of the dynamics is quantified by a length, characteristic of cooperativity within the flow at these scales, that is unobservable in the liquid state (lower emulsion concentrations) and that increases with concentration in the jammed state. Beyond its practical importance for applications involving thin layers (for example, coatings), these non-locality and cooperativity effects have parallels in the behaviour of other glassy, jammed and granular systems, suggesting a possible fundamental universality.

Spatial cooperativity in soft glassy flows

A kinetic model for the elastoplastic dynamics of a jammed material is proposed, which takes the form of a nonlocal---Boltzmann-like---kinetic equation for the stress distribution function. Coarse graining this equation yields a nonlocal constitutive law for the flow, exhibiting as a key dynamic quantity the local rate of plastic events. This quantity, interpreted as a local fluidity, is spatially correlated with a correlation length diverging in the quasistatic limit, i.e., close to yielding. In line with recent experimental and numerical observations, we predict finite size effects in the flow behavior, as well as the absence of an intrinsic local flow curve.

http://ilm-perso.univ-lyon1.fr/~lbocquet/PRL-Bocquet-2009.pdf

Kinetic theory of plastic flow in soft glassy materials.

Motivated by its importance for microfluidic applications, we study the stability of jets formed by pressure-driven concentric biphasic flows in cylindrical capillaries. The specificity of this variant of the classical Rayleigh-Plateau instability is the role of the geometry which imposes confinement and Poiseuille flow profiles. We experimentally evidence a transition between situations where the flow takes the form of a jet and regimes where drops are produced. We describe this as the transition from convective to absolute instability, within a simple linear analysis using lubrication theory for flows at low Reynolds number, and reach remarkable agreement with the data.

Stability of a Jet in Confined Pressure-Driven Biphasic Flows at Low Reynolds Numbers

In this work, the flow of immiscible fluids in microchannels is studied. Flow pattern diagrams obtained in microfluidic chips are presented. Monodisperse droplets or parallel flows are obtained depending on the flow rate values of the aqueous phase and the oil phase. Transition from droplet regime to parallel flows cannot be described in terms of capillary numbers. Using confocal microscopy and high speed imaging, it was shown that droplets are formed through a blocking-pinching mechanism ruled by flow rate conservation. Conditions for parallel flow stability are quantified.

Annie Colin

Papers

Evidence for three-dimensional unstable flows in shear-banding wormlike micelles.

Spatial cooperativity in soft glassy flows

Kinetic theory of plastic flow in soft glassy materials.

Stability of a Jet in Confined Pressure-Driven Biphasic Flows at Low Reynolds Numbers

Stability of parallel flows in a microchannel after a T junction.