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Anthony F. Hegarty
Researcher at University College Dublin
Publications - 180
Citations - 2098
Anthony F. Hegarty is an academic researcher from University College Dublin. The author has contributed to research in topics: Nucleophile & Aqueous solution. The author has an hindex of 23, co-authored 180 publications receiving 2035 citations. Previous affiliations of Anthony F. Hegarty include Katholieke Universiteit Leuven & University College Cork.
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The Alcoholysis Reaction of Isocyanates Giving Urethanes: Evidence for a Multimolecular Mechanism.
TL;DR: Experimental and theoretical results showed that the alcoholysis should be understood by a multimolecular intervention of the alcohols, and theoretical study suggests an active participation of at least three alcohol molecules in a reacting supersystem, giving rise to a genuine effect.
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Can the pentazole anion (N5−) be isolated and/or trapped in metal complexes?
TL;DR: In this article, the 1,3-dipolar cycloreversion pathway of the pentazole anion (N 5 − ) to the azide anion plus dinitrogen (N 2 ) has been investigated using ab initio methods.
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Experimental and Theoretical Evidence for a Concerted Catalysis by Water Clusters in the Hydrolysis of Isocyanates.
TL;DR: Experimental results imply a second-order dependence on water during its nucleophilic addition to phenyl isocyanate, over a wide concentration range.