Embodiments of this disclosure pertain to articles that exhibit scratch-resistance and improved optical properties. In some examples, the article exhibits a color shift of about 2 or less, when viewed at an incident illumination angle in the range from about 0 degrees to about 60 degrees from normal under an illuminant. In one or more embodiments, the articles include a substrate, and an optical film disposed on the substrate. The optical film includes a scratch-resistant layer and an optical interference layer. The optical interference layer may include one or more sub-layers that exhibit different refractive indices. In one example, the optical interference layer includes a first low refractive index sub-layer and a second a second high refractive index sub-layer. In some instances, the optical interference layer may include a third sub-layer.

Low-color scratch-resistant articles with a multilayer optical film

Embodiments of durable, anti-reflective articles are described. In one or more embodiments, the article includes a substrate and an optical coating disposed on the major surface. The optical coating includes an anti-reflective coating and a scratch-resistant coating forming an anti-reflective surface. The article exhibits a maximum hardness of 12 GPa or greater, as measured on the anti-reflective surface by a a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm or greater. The articles of some embodiments exhibit a single side average light reflectance measured at the anti-reflective surface of about 8% or less over an optical wavelength regime in the range from about 400 nm to about 800 nm and a reference point color shift in transmittance or reflectance of less than about 2. In some embodiments, the article exhibits an angular color shift of about 5 or less at all angles from normal incidence to an incident illumination angle that is 20 degrees or greater.

Durable and scratch-resistant anti-reflective articles

One or more aspects of the disclosure pertain to an article including an optical film structure disposed on an inorganic oxide substrate, which may include a strengthened or non-strengthened substrate that may be amorphous or crystalline, such that the article exhibits scratch resistance and retains the same or improved optical properties as the inorganic oxide substrate, without the optical film structure disposed thereon. In one or more embodiments, the article exhibits an average transmittance of 85% or more, over the visible spectrum (e.g., 380 nm-780 nm). Embodiments of the optical film structure include aluminum-containing oxides, aluminum-containing oxy-nitrides, aluminum-containing nitrides (e.g., AlN) and combinations thereof. The optical film structures disclosed herein also include a transparent dielectric including oxides such as silicon oxide, germanium oxide, aluminum oxide and a combination thereof. Methods of forming such articles are also provided.

Scratch-resistant articles with retained optical properties

The disclosure is directed to piezoelectric film structures and sensors, and display assemblies using same. The piezoelectric film structure is transparent and includes: a substrate; a bottom optical layer disposed on or above the substrate; a bottom conducting layer disposed on or above the bottom optical layer; at least one piezoelectric layer disposed on or above the bottom conducting layer; a top conducting layer disposed on or above the at least one piezoelectric layer; and a top optical layer disposed on or above the top conducting layer. The sensor includes the piezoelectric film structure electrically connected to a signal processing system. The display assembly includes the sensor operably arranged relative to a display device. The piezoelectric film structures and sensors can be configured to determine one or more touch-sensing features associated with a touch event.

Piezoelectric film structures and sensors and display assemblies using the same

Embodiments of articles including a low-contrast anti-reflection coating are disclosed. The coated surface of such articles exhibits a reduced difference in reflectance between a pristine state and when a surface defect is present. In one or more embodiments, the coated surface of such articles exhbits a first average reflectance in the range from about 0.6% to about 6.0% in a pristine condition and a second avearge reflectance of about 8% or less after removal of a surface thickness of the anti-reflection coating. In other embodiments, the coated substrate exhibits a second average reflectance of about 10% or less, when the coated surface comprises a contaiminant. In some embodiments, the coated substrate exhibits a first color coordinate (a* 1 , b* 1 ) in a pristine condition and a second color coordinate (a* 2 , b* 2 ) after the presence of a surface defect such that Δa*b* is about 6 or less.

Low contrast anti-reflection articles with reduced scratch and fingerprint visibility

Embodiments of this disclosure pertain to articles that exhibit scratch-resistance and improved optical properties. In some examples, the article exhibits a color shift of about 2 or less, when viewed at an incident illumination angle in the range from about 0 degrees to about 60 degrees from normal under an illuminant. In one or more embodiments, the articles include a substrate, and an optical film disposed on the substrate. The optical film includes a scratch-resistant layer and a refractive index gradient. In one or more embodiments, the refractive index includes a refractive index that increases from a first surface at the interface between the substrate and the optical film to a second surface. The refractive index gradient may be formed from a compositional gradient and/or a porosity gradient.

Scratch-resistant articles with a gradient layer

To provide articles that exhibit scratch- resistance and improved optical properties.SOLUTION: In some embodiments of the invention, an article (100) exhibits color shift of about 2 or less, when viewed at an incident illumination angle in a range from about 0 degrees to about 60 degrees from normal incidence under an illuminant. In one or more embodiments, the articles (100) include a substrate (110), and an optical film (120) disposed on the substrate. The optical film includes a scratch-resistant layer (140) and a refractive index gradient. In one or more embodiments, the refractive index includes a refractive index that increases from a first surface (122) at an interface between the substrate and the optical film to a second surface (124). The refractive index gradient may be formed from a compositional gradient and/or a porosity gradient.SELECTED DRAWING: Figure 6

Arthur Sachenik Paul

Papers

Scratch-resistant articles with a gradient layer

Scratch-resistant articles with gradient layer