This article provides an up-to-date perspective on the use of anion-exchange membranes in fuel cells, electrolysers, redox flow batteries, reverse electrodialysis cells, and bioelectrochemical systems (e.g. microbial fuel cells). The aim is to highlight key concepts, misconceptions, the current state-of-the-art, technological and scientific limitations, and the future challenges (research priorities) related to the use of anion-exchange membranes in these energy technologies. All the references that the authors deemed relevant, and were available on the web by the manuscript submission date (30th April 2014), are included.

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Anion-exchange membranes in electrochemical energy systems

We present a study on the catalytic reduction of 4-nitrophenol by sodium borohydride in the presence of metal nanoparticles. The nanoparticles are embedded in spherical polyelectrolyte brushes, which consist of a polystyrene core onto which a dense layer of cationic polyelectrolyte brushes are grafted. The average size of the nanoparticles is approximately 2 nm. The kinetic data obtained by monitoring the reduction of 4-nitrophenol by UV/vis-spectroscopy could be explained in terms of the Langmuir−Hinshelwood model: The borohydride ions transfer a surface-hydrogen species in a reversible manner to the surface. Concomitantly 4-nitrophenol is adsorbed and the rate-determining step consists of the reduction of nitrophenol by the surface-hydrogen species. The apparent reaction rate can therefore be related to the total surface S of the nanoparticles, to the kinetic constant k related to the rate-determining step, and to the adsorption constants KNip and KBH4 of nitrophenol and of borohydride, respectively. In...

Kinetic Analysis of Catalytic Reduction of 4-Nitrophenol by Metallic Nanoparticles Immobilized in Spherical Polyelectrolyte Brushes

Catalysis by metallic nanoparticles is certainly among the most intensely studied problems in modern nanoscience. However, reliable tests for catalytic performance of such nanoparticles are often poorly defined, which makes comparison and benchmarking rather difficult. We tackle in this tutorial review a subset of well-studied reactions that take place in aqueous phase and for which a comprehensive kinetic analysis is available. Two of these catalytic model reactions are under consideration here, namely the reduction of (i) p-nitrophenol and (ii) hexacyanoferrate (III), both by borohydride ions. Both reactions take place at the surface of noble metal nanoparticles at room temperature and can be accurately monitored by UV-vis spectroscopy. Moreover, the total surface area of the nanoparticles in solution can be known with high precision and thus can be directly used for the kinetic analysis. Hence, these model reactions represent cases of heterogeneous catalysis that can be modelled with the accuracy typically available for homogeneous catalysis. Both model reactions allow us to discuss a number of important concepts and questions, namely the dependence of catalytic activity on the size of the nanoparticles, electrochemistry of nanoparticles, surface restructuring, the use of carrier systems and the role of diffusion control.

Catalysis by metallic nanoparticles in aqueous solution: model reactions.

An Fe-doped CoP nanoarray behaves as a robust 3D monolithic multifunctional catalyst for electrolytic and hydrolytic hydrogen evolution with high activity Its two-electrode electrolyzer needs a cell voltage of only 160 V for 10 mA cm-2 water-splitting current It also catalyzes effectively NaBH4 hydrolysis with a low activation energy of ≈396 kJ mol-1 and a hydrogen generation rate of 606 L min-1 g-1 

Fe-Doped CoP Nanoarray: A Monolithic Multifunctional Catalyst for Highly Efficient Hydrogen Generation

In the search for future energy supplies, the application of hydrogen as an energy carrier is seen as a prospective issue. However, the implementation of a hydrogen economy is suffering from several unsolved problems. Particularly challenging is the storage of appropriate amounts of hydrogen. In this context one of the promising hydrogen storage techniques relies on liquid-phase chemical hydrogen storage materials, in particular, aqueous sodium borohydride, ammonia borane, hydrazine, hydrazine borane and formic acid. The use of these materials in hydrogen storage provides high gravimetric and volumetric hydrogen densities, low potential risk, and low capital investment because it is largely compatible with the current transport infrastructure. In this review, we survey the research progresses in hydrogen generation from these liquid-phase chemical hydrogen storage materials and their regeneration.

B.H. Liu

Papers

A review: Hydrogen generation from borohydride hydrolysis reaction

Current status and progress of direct borohydride fuel cell technology development

A micro-reactor with micro-pin-fin arrays for hydrogen production via methanol steam reforming

Depression of hydrogen evolution during operation of a direct borohydride fuel cell

A multi functional binder with lithium ion conductive polymer and polysulfide absorbents to improve cycleability of lithium–sulfur batteries