Biswajit Guchhait

TL;DR: Representative all-atom molecular dynamics simulations of (CH3CONH2 + LiX) DEs at different temperatures reveal strongly stretched exponential relaxation of wavevector dependent acetamide self dynamic structure factor with time constants dependent both on ion identity and temperature, providing justification for explaining the fluorescence results in terms of temporal heterogeneity and amide clustering in these multi-component melts.

TL;DR: The theoretically predicted solvation response function in the overdamped limit at each mixture composition has been found to be triexponential and the calculations in the underdamped limit, however, suggest a biphasic decay.

TL;DR: Estimated experimental dynamic Stokes shift for coumarin 153 in these mixtures lies in the range, 1000 < Δν(t)/cm(-1) < 1700, and is in semi-quantitative agreement with predictions from the authors' semi-molecular theory.

TL;DR: In this article, a polar solute probe in molten (CH3CONH2+Ca(NO3)2·4.37H2O) mixtures has been measured in order to probe the solute-medium interactions in such complex systems.

TL;DR: The different interactions of limited strength ensure ultrafast vibrational relaxation and dissipation of excess energy in the backbone structure, processes that are important for the structural integrity of hydrated DNA.