Showing papers by "Bryan M. Gatehouse published in 1974"
TL;DR: The title compound of as mentioned in this paper crystallizes in the monoclinic space group P21, with a= 8·629(5), b= 10·755(8), c= 11·116(9)A, β= 107·2(1)°, and Z= 2.
Abstract: The title compound crystallizes in the monoclinic space group P21, with a= 8·629(5), b= 10·755(8), c= 11·116(9)A, β= 107·2(1)°, and Z= 2. The structure has been determined from diffractometer data by Patterson and Fourier methods and refined to R 0·048 for 1967 independent non-zero reflections. The crystals are built up of discrete molecules, the palladium atom having approximate square planar geometry, with the two nitrogen atoms mutually trans. Bond distances are : Pd–O 2·094, Pd–N(1)(imine) 2·037, Pd–N(2)(amine) 2·090, and Pd–C(16) 1·981 A.
12 citations
TL;DR: The compound [Cr2(CO)6(AsMe)9] as discussed by the authors contains a nine-membered As ring co-ordinated to each Cr atom through three As atoms.
Abstract: The compound [Cr2(CO)6(AsMe)9] contains a nine-membered As ring co-ordinated to each Cr atom through three As atoms while [Mo2(CO)6(AsPrn)8] contains a chain of eight As atoms with terminal As atoms bridging both metal atoms and one other arsenic atom in the chain also co-ordinated to each metal, together with an Mo–Mo bond.
9 citations
TL;DR: The title compound of as mentioned in this paper crystallizes in space group P21/c with a= 6·429(6), b= 13·619(14), c= 10·047(10)A, β= 107·88(1)°, Z= 2.
Abstract: The title compound crystallizes in space group P21/c with a= 6·429(6), b= 13·619(14), c= 10·047(10)A, β= 107·88(1)°, Z= 2. The structure has been determined by Patterson and Fourier methods and refined to R 0·057 from three-dimensional diffractometer data (1325 observed reflections). Its structure consists of discrete monomeric units which are required crystallographically to be centrosymmetric. The two chlorine atoms are in a trans arrangement and the bond distances Mo–Cl, Mo–O, and Mo–N are respectively 2·39, 1·95, and 2·14 A.
8 citations
TL;DR: The title compound of as discussed by the authors crystallizes in space group P21/c with a= 6·429(6), b= 13·619(14), c= 10·047(10)A, β= 107·88(1)°, Z= 2.
Abstract: The title compound crystallizes in space group P21/c with a= 6·429(6), b= 13·619(14), c= 10·047(10)A, β= 107·88(1)°, Z= 2. The structure has been determined by Patterson and Fourier methods and refined to R 0·057 from three-dimensional diffractometer data (1325 observed reflections). Its structure consists of discrete monomeric units which are required crystallographically to be centrosymmetric. The two chlorine atoms are in a trans arrangement and the bond distances Mo–Cl, Mo–O, and Mo–N are respectively 2·39, 1·95, and 2·14 A.