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C.T. Mortimer

Researcher at Keele University

Publications -  22
Citations -  139

C.T. Mortimer is an academic researcher from Keele University. The author has contributed to research in topics: Bond strength & Thermal decomposition. The author has an hindex of 7, co-authored 22 publications receiving 139 citations.

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Journal ArticleDOI

Platinumolefin bond strength in Pt(PPh3)2(CH2CH2) and Pt(PPh3)2 {C(CN)2C(CN)2}

TL;DR: In this article, the enthalpy of the reaction was determined as Δ H 298 =−155.8±8.0 kJ·mol −1, from solution calorimetry.
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The thermal decomposition of transition-metal complexes containing heterocyclic ligands: 3. Substituted pyridine complexes of cobalt

TL;DR: In this paper, the enthalpies of the overall decomposition reactions CoX 2 L 2 (c) → CoX2 (c)+2L(g) and of the intermediate stepwise loss of ligand, L, where X is Cl or Br, and L is 3-chloropyridine, 3-bromopyrine, 2-methoxypyridine (2-chloropeyridine), 2-chloropyropyridine and 2-methylpyridine have been measured using a differential scanning calorimeter.
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The platinium—carbon bond strength in Pt(PPh3)2(CPhCPh)

TL;DR: The enthalpy of the reaction: Pt(PPh3)2(CH2CH2)(cryst) + CPhCPh(cryst.) → PPh32(CPhCPh) + CH2CH2(g) has been determined as /gDH298 = −82 ∓ 12 kJ mol−1, from solution calorimetry as mentioned in this paper.
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The platinumcarbon bond strength in Pt(PPh3)2(CH3)I

TL;DR: In this paper, the enthalpies of reaction 1-3 were determined as Δ H (1) = −176.6 ± 5.4, Δ H 2 = −107.8 ± 6.0 and Δ H 3 = −78.9 ± 2.0 kJ mol −1.