Sonochemistry is the use of ultrasound to enhance or alter chemical reactions. Sonochemistry in the true sense of the term occurs when ultrasound induces “true” chemical effects on the reaction system, such as forming free radicals which accelerate the reaction. However, ultrasound may have other mechanical effects on the reaction, such as increasing the surface area between the reactants, accelerating dissolution, and/or renewing the surface of a solid reactant or catalyst. This comprehensive review summarizes several topics of study in the sonochemical literature, including bubble dynamics, factors affecting cavitation, the effects of ultrasound on a variety of chemical systems, modeling of kinetic and mass-transfer effects, the methods used to produce ultrasound, proposed cavitation reactors, and the problems of scaleup. The objective of this paper is to present a critical review of information available in the literature so as to facilitate and inspire future research in the field of sonochemistry.

Sonochemistry: Science and Engineering

In order to elucidate the mechanism of cavitation erosion, the dynamics of a single laser-generated cavitation bubble in water and the resulting surface damage on a flat metal specimen are investigated in detail. The characteristic effects of bubble dynamics, in particular the formation of a high-speed liquid jet and the emission of shock waves at the moment of collapse are recorded with high-speed photography with framing rates of up to one million frames/s. Damage is observed when the bubble is generated at a distance less than twice its maximum radius from a solid boundary (γ=2, where γ=s/Rmax, s is the distance between the boundary and the bubble centre at the moment of formation and Rmax is the maximum bubble radius). The impact of the jet contributes to the damage only at small initial distances (γ[les ]0.7). In this region, the impact velocity rises to 83 m s−1, corresponding to a water hammer pressure of about 0.1 GPa, whereas at γ>1, the impact velocity is smaller than 25 m s−1. The largest erosive force is caused by the collapse of a bubble in direct contact with the boundary, where pressures of up to several GPa act on the material surface. Therefore, it is essential for the damaging effect that bubbles are accelerated towards the boundary during the collapse phases due to Bjerknes forces. The bubble touches the boundary at the moment of second collapse when γ<2 and at the moment of first collapse when γ<1. Indentations on an aluminium specimen are found at the contact locations of the collapsing bubble. In the range γ=1.7 to 2, where the bubble collapses mainly down to a single point, one pit below the bubble centre is observed. At γ[les ]1.7, the bubble shape has become toroidal, induced by the jet flow through the bubble centre. Corresponding to the decay of this bubble torus into multiple tiny bubbles each collapsing separately along the circumference of the torus, the observed damage is circular as well. Bubbles in the ranges γ[les ]0.3 and γ=1.2 to 1.4 caused the greatest damage. The overall diameter of the damaged area is found to scale with the maximum bubble radius. Owing to the possibility of generating thousands of nearly identical bubbles, the cavitation resistance of even hard steel specimens can be tested.

Cavitation erosion by single laser-produced bubbles

Revue de resultats experimentaux et theoriques concernant l'effondrement de bulles de cavitation pres de frontieres rigides, de surfaces libres, d'interfaces entre deux fluides de densites differentes et de materiaux composites

Cavitation Bubbles Near Boundaries

Cavitation bubbles were produced by focusing giant pulses of a Q-switched ruby laser into distilled water. The dynamics of the bubbles in the neighbourhood of a solid boundary were studied by means of high-speed photography using a rotating-mirror camera with framing rates of up to 300000 frame/s. Bubble motion was evaluated from the frames with the aid of a digital computer using a graphical input device. Smoothed distance-time curves of different portions of the bubble wall were obtained also, allowing a reliable calculation of bubble-wall velocities (except at the actual instant of collapse). One of the numerical examples of the collapse of a spherical bubble near a plane solid boundary obtained by Plesset & Chapman could be realized experimentally. A comparison of the bubble shapes shows good agreement.

Experimental investigations of cavitation-bubble collapse in the neighbourhood of a solid boundary

The dynamics of laser-produced cavitation bubbles near a solid boundary and its dependence on the distance between bubble and wall are investigated experimentally. It is shown by means of high-speed photography with up to 1 million frames/s that jet and counterjet formation and the development of a ring vortex resulting from the jet flow are general features of the bubble dynamics near solid boundaries. The fluid velocity field in the vicinity of the cavitation bubble is determined with time-resolved particle image velocimetry. A comparison of path lines deduced from successive measurements shows good agreement with the results of numerical calculations by Kucera & Blake (1988). The pressure amplitude, the profile and the energy of the acoustic transients emitted during spherical bubble collapse and the collapse near a rigid boundary are measured with a hydrophone and an optical detection technique. Sound emission is the main damping mechanism in spherical bubble collapse, whereas it plays a minor part in the damping of aspherical collapse. The duration of the acoustic transients is 20-30 ns. The highest pressure amplitudes at the solid boundary have been found for bubbles attached to the boundary. The pressure inside the bubble and at the boundary reaches about 2.5 kbar when the maximum bubble radius is 3.5 mm. The results are discussed with respect to the mechanism of cavitation erosion.

Optical and acoustic investigations of the dynamics of laser-produced cavitation bubbles near a solid boundary

A perfect fluid perturbation theory, which neglects the effect of gravity, and which assumes that the pressure inside a cavitation bubble remains constant during the collapse process, is given for the case of a non-hemispherical, but axially symmetric cavity which collapses in contact with a solid boundary. The theory suggests the possibility that such cavities may deform to the extent that the cavity wall strikes the solid surface before minimum cavity volume is reached.

High speed motion pictures of cavities generated by spark methods are used to test the theory experimentally. It is found that the theory describes the change of shape of such cavities fairly well, and that the phenomenon of the cavity wall striking the solid boundary does indeed occur.

By studying the damaging effects of various cavities of this type on aluminum samples, it is shown that pressures resulting from the cavity wall striking the surface are much higher than pressures caused by compression of gases inside the cavity. It is furthermore found that the estimated impact velocities of the cavity walls on the solid boundary can account for water hammer pressures sufficiently large to have caused the observed damage.

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Charl F. Naudé

Papers

On the Mechanism of Cavitation Damage by Nonhemispherical Cavities Collapsing in Contact With a Solid Boundary