Palladium-catalysed reactions of aryl halides with soft, non-organometallic nucleophiles

Palladium-catalyzed phosphination of functionalized aryl triflates

Application of palladium-catalyzed Pd-aryl/P-aryl exchanges: preparation of functionalized aryl phosphines by phosphination of aryl bromides using triarylphosphines

https://www.jbc.org/content/280/18/18291.full.pdf

Covalent Cross-links between the γ Subunit (FXYD2) and α and β Subunits of Na,K-ATPase MODELING THE α-γ INTERACTION

The use of palladium catalysts derived from 1,1′-bis-diisopropylphosphino-ferrocene and a microwave heating source allows the coupling of a range of ortho-substituted aryl bromides to diphenylphosphine derivatives to proceed in good yield in under 30 min. Optimization studies reveal that the combination of diphenylphosphine and DABCO is superior to more basic phosphide nucleophiles such as Ph2PK or Ph2PMgBr. High yields are only observed when moderately bulky electron rich diphosphines are used as ligands. The differences between PC coupling and other cross-coupling reactions are discussed in the light of the reactivity observed. Studies aimed at producing industrially important 1,2-bis-phosphino-benzene ligands are also described. Copyright © 2009 John Wiley & Sons, Ltd.

Palladium‐catalysed PC bond forming reactions between diphenylphosphine and ortho‐substituted aryl bromides

Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester†

Christoph Vedder

Papers

Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester†