Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts

FeS2/MoS2@RGO hybrid materials derived from polyoxomolybdate-based metal–organic frameworks as high-performance electrocatalyst for ammonia synthesis under ambient conditions

Reticular frameworks including metal−organic frameworks (MOFs) and covalent organic frameworks (COFs), and their derived materials have drawn global attention in the capture and conversion of CO2 as a cheap feedstock into fine chemicals and fuels due to their facile synthesis and programmable highly porous structures. This review comprehensively summarizes the progress in thermo−catalysis of CO2 conversion by reticular framework−based catalysts to afford chemicals such as cyclic carbonates, cyclic carbamates, formamides, carboxylic acid, carbon monoxide, formate, methanol, methane, and light olefins. Firstly, the characteristics and advantages of MOF−based materials for CO2 conversion are introduced. Secondly, the characteristics and advantages of COF−based materials for CO2 conversion are presented. Subsequently, the CO2 conversion reactions are briefly classified and discussed. Particularly, MOF or COF−based catalysts for each reaction are summarized in terms of catalyst design, catalytic performance and catalytic mechanism. Finally, the perspectives for further development of reticular framework−based catalysts for efficient CO2 conversion are discussed. We hope this review can provide an inspiration for the rational design of porous crystalline materials for thermal catalytic CO2 conversion.

Reticular frameworks and their derived materials for CO2 conversion by thermo−catalysis

Design and construction of core-shell heterostructure of Ni-V layered double hydroxide composite electrode materials for high-performance hybrid supercapacitor and L-Tryptophan sensor

Chunyan Zhao

Papers

A polyoxometalate-encapsulated nanocage cluster organic framework built from {Cu4P2} units and its efficient bifunctional electrochemical performance

Design catalytic space engineering of Ag-Ag bond-based metal organic framework for carbon dioxide fixation reactions

A new polyoxometalate-based helical compound with entanglement nodes: Structure, electrocatalytic and photocatalytic properties