TiVCrAlSi high entropy alloy coatings were deposited on Ti–6Al–4V alloy by laser cladding. SEM, XRD and EDS analyses show that, the as-clad coating is composed of (Ti,V) 5 Si 3 and a BCC solid solution. After annealing at 800 °C for 24 h under vacuum, the coating is composed of (Ti,V) 5 Si 3 , Al 8 (V,Cr) 5 , and a BCC solid solution. The temperature-dependent phase equilibrium for the coating material calculated by using the CALPHAD method, indicates that above 880 °C the stable phases existing in the coating material are a BCC solid-solution and (Ti,V) 5 Si 3 . When the temperature is below 880 °C, the stable phases are (Ti,V) 5 Si 3 , Al 8 (V,Cr) 5 , and a BCC solid solution. In order to validate the calculation results, they were compared with TiVCrAlSi alloy samples prepared by arc melting, encapsulated in quartz tubes under vacuum, annealed at 400–1100 °C for 3 days and water-quenched. XRD analysis shows that the experimental phase composition agrees with the thermodynamic calculations. After vacuum annealing, there is a small increase of hardness for the laser clad TiVCrAlSi coating, which is due to the formation of Al 8 (V,Cr) 5 . The oxidation tests show that the TiVCrAlSi coating effectively improves the oxidation resistance of Ti–6Al–4V at 800 °C in air. The formation of a dense and adherent scale consisting of SiO 2 , Cr 2 O 3 , TiO 2 , Al 2 O 3 and a small amount of V 2 O 5 is supposed to be responsible for the observed improvement of the oxidation resistance.

Thermal stability and oxidation resistance of laser clad TiVCrAlSi high entropy alloy coatings on Ti–6Al–4V alloy

Metallic Functionally Graded Materials: A Specific Class of Advanced Composites

The corrosion susceptibility of a laser powder bed fusion (LPBF) additively manufactured alloy, UNS S17400 (17-4 PH), was explored compared to conventional wrought material. Microstructural charact...

Corrosion Properties of Powder Bed Fusion Additively Manufactured 17-4 PH Stainless Steel

Two and three-dimensional characterisation of localised corrosion affected by lack-of-fusion pores in 316L stainless steel produced by selective laser melting

Slurry erosive wear behaviour of thermally sprayed Inconel-718 coatings by APS process

The oxidation and erosion–oxidation (E–O) behaviour of high velocity oxy fuel sprayed Ni–20Cr alloy as well as WC and Cr3C2 cermet coatings on a steel substrate were studied. The E–O tests were carried out in a rig with specimen assemblies that were rotated through a fluidized bed of erodent particles in the temperature range 500–850°C and with erodent impact velocities of 2·5– 19·5 m s−1. Alumina powder (∼200 μm) was used as the erodent. The oxidation behaviour of the coatings was determined gravimetrically. The Ni–20Cr and Cr3C2–25(Ni–20Cr) coatings showed significantly higher oxidation resistance than the WC–20Cr–7Ni coating, especially at temperatures above 800°C. The E–O resistance of the coatings was determined by wastage, as a function of temperature. The three coatings did not show any significant change in E–O at temperatures up to 500–600°C. At higher temperatures, wastage increased with temperature, reached a maximum at 700°C and then decreased with further increase in temperature. Diff...

High temperature oxidation and erosion–oxidation behaviour of HVOF sprayed Ni–20Cr, WC–20Cr–7Ni and Cr3C2–Ni–20Cr coatings

The corrosion resistance of 17-4PH powder injection-molded (PIM) martensitic stainless steel (SS) was evaluated in naturally aerated sodium chloride (NaCl) solution (3 wt%) at 25°C. This resistance was investigated by analyzing the curves of the evolution of open-circuit potential with time (Eocp vs. time), electrochemical impedance spectroscopy (EIS), and surface observation by scanning electron microscopy (SEM) at increasing times of immersion. The susceptibility to pitting was investigated using cyclic potentiodynamic polarization curves and SEM observation after polarization. Additionally, the susceptibility to intergranular corrosion was evaluated by a modified procedure described in ASTM A 262 Practice A. The results of the 17-4PH PIM steel were compared to that of a 17-4PH steel produced by conventional metallurgy. The results showed that under steady-state conditions the PIM steel presented a behavior typical of passive metals during the whole test period (60 days of immersion). This was ...

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Corrosion Resistance of Injection-Molded 17-4PH Steel in Sodium Chloride Solution

In this investigation the corrosion resistance of four Al-Si hypereutectic alloys in a solution typical of condensate from automotive fuel combustion products, and referred to here as synthetic condensed automotive solution, has been studied. Three commercial alloys that are used for cylinder liners, and a laboratory made alloy, were studied by electrochemical impedance spectroscopy and measurements were taken after increasing times of immersion in this solution. Comparison of the electrochemical response of the four alloys in the corrosive solution was carried out. Although the mechanisms by which the four alloys corroded were similar, the results indicated differences in corrosion resistances of these alloys, and these differences could be related to their microstructures. The laboratory prepared alloy showed increased susceptibility to pitting corrosion compared to the commercial alloys. The surfaces of the alloys were examined, before and after the corrosion test, by scanning electron microscopy and analyzed by energy dispersive spectroscopy. The results indicated preferential attack of the aluminium matrix phase in all the alloys. The alloy with higher copper content and prepared by spray forming was more susceptible to pitting compared to the other alloys. The EIS response at low frequencies indicated a diffusion-controlled process, probably that of oxygen to the alloy interface.

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Corrosion performance of Al-Si-Cu hypereutectic alloys in a synthetic condensed automotive solution

An apparatus to conduct high temperature erosion-oxidation studies up to 850 °C and with particle impact velocities up to 15 m.s-1 was designed and constructed in the Corrosion Laboratories of IPEN. The erosion-oxidation behavior of high velocity oxy fuel (HVOF) sprayed alloy and cermet coatings of Ni20Cr, WC 20Cr7Ni and Cr3C2 Ni20Cr on a steel substrate has been studied. Details of this apparatus and the erosion-oxidation behavior of these coatings are presented and discussed. The erosion-oxidation behavior of HVOF coated Cr3C2 25(Ni20Cr) was better than that of WC 20Cr7Ni, and the erosion-oxidation regimes have been identified for these coatings at particle impact velocity of 3.5 m.s-1, impact angle of 90° and temperatures in the range 500 to 850 °C.

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Erosion-oxidation behavior of thermal sprayed Ni20Cr alloy and WC and Cr3C2 cermet coatings

Al-Si hypereutectic alloys produced by spray forming represent an important technological development for application in the aeronautical and automotive industries. Due to some special properties these alloys find application as cylinder liners, mainly due to their high strength and wear resistance. Much research has been carried out to evaluate the mechanical properties of these alloys but the literature on their corrosion performance is still very scarce. In this study, the corrosion behaviour of a spray formed Al-Si-Cu hypereutectic alloy was investigated by electrochemical impedance spectroscopy (EIS) in acid (pH 3.3), neutral (pH 7) and alkaline (pH 11) solutions. Intense localized attack occurred in the acid electrolyte and the impedance decreased with time of immersion. In the neutral medium, the alloy was passivated but localized attack also occurred on weak areas of the passive film. In the alkaline medium, precipitation of corrosion products occurred during the first hours of immersion causing the increase of impedance but thickening of this layer led to cracks growth with time and, consequently, to the exposure of metallic substrate, resulting in the decrease in impedance for longer periods.

Clarice Terui Kunioshi

Papers

High temperature oxidation and erosion–oxidation behaviour of HVOF sprayed Ni–20Cr, WC–20Cr–7Ni and Cr3C2–Ni–20Cr coatings

Corrosion Resistance of Injection-Molded 17-4PH Steel in Sodium Chloride Solution

Corrosion performance of Al-Si-Cu hypereutectic alloys in a synthetic condensed automotive solution

Erosion-oxidation behavior of thermal sprayed Ni20Cr alloy and WC and Cr3C2 cermet coatings

The corrosion behaviour of a hypereutectic Al-Si alloy obtained by spray forming in acid, neutral and alkaline solutions