Efficient and low-cost transition metal single-atom catalysts (TMSACs) for hydrogen evolution reaction (HER) have been recognized as research hotspots recently with advances in delivering good catalytic activity without noble metals. However, the high-cost complex preparation of TMSACs and insufficient stability limited their practical applications. Herein, a simple top-down pyrolysis approach to obtain P-modified Co SACs loaded on the crosslinked defect-rich carbon nanosheets was introduced for alkaline hydrogen evolution, where Co atoms are locally confined before pyrolysis to prevent aggregation. Thereby, the abundant defects and the unsaturated coordination formed during the pyrolysis significantly improved the stability of the monatomic structure and reduced the reaction barrier. Furthermore, the synergy between cobalt atoms and phosphorus atoms was established to optimize the decomposition process of water molecules, which delivers the key to promoting the slow reaction kinetics of alkaline HER. As the result, the cobalt SAC exhibited excellent catalytic activity and stability for alkaline HER, with overpotentials of 70 mV and 192 mV at current densities of -10 mA cm-2 and -100 mA cm-2, respectively.

Phosphorus-modified cobalt single-atom catalysts loaded on crosslinked carbon nanosheets for efficient alkaline hydrogen evolution reaction.

The role of selenium vacancies functionalized mediator of bimetal (Co, Fe) selenide for high-energy-density lithium-sulfur batteries.

Tribological aspects of the Diamond-like carbon film applied to different surfaces of AISI M2 steel

Probing the low friction mechanism of hydrogen-free DLC film in oxygen and nitrogen environments by first-principles calculations and molecular dynamics simulation

Effect of graphene oxide or triethanolamine-modified graphene oxide on the hydration of calcium sulfoaluminate cement

Deconvolution process approach in Raman spectra of DLC coating to determine the sp3 hybridization content using the ID/IG ratio in relation to the quantification determined by X-ray photoelectron spectroscopy

Clements, Jourdan

Papers

Deconvolution process approach in Raman spectra of DLC coating to determine the sp3 hybridization content using the ID/IG ratio in relation to the quantification determined by X-ray photoelectron spectroscopy