ZnO nanowires (or nanorods) have been widely studied due to their unique material properties and remarkable performance in electronics, optics, and photonics. Recently, photocatalytic applications of ZnO nanowires are of increased interest in environmental protection applications. This paper presents a review of the current research of ZnO nanowires (or nanorods) with special focus on photocatalysis. We have reviewed the semiconducting photocatalysts and discussed a variety of synthesis methods of ZnO nanowires and their corresponding effectiveness in photocatalysis. We have also presented the characterization of ZnO nanowires from the literature and from our own measurements. Finally, a wide range of uses of ZnO nanowires in various applications is highlighted in this paper.

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Synthesis, characterization, and applications of ZnO nanowires

Comprehensive analysis of energy, exergy and exergo-economic of cogeneration of heat and power in a combined gas turbine and organic Rankine cycle

Thermoeconomic analysis and optimization of an ammonia–water power/cooling cogeneration cycle

https://www.seas.upenn.edu/~lior/documents/EnergyexergyandSecondLawperformancecriteriapublished.pdf

Energy, exergy, and Second Law performance criteria

One dimensional-ZnO nanostructures: Synthesis, properties and environmental applications

A combined power and cooling cycle is being investigated. The cycle is a combination of the Rankine cycle and an absorption refrigeration cycle. Evaluating the efficiency of this cycle is made difficult by the fact that there are two different simultaneous outputs, namely power and refrigeration. An efficiency expression has to appropriately weigh the cooling component in order to allow comparison of this cycle with other cycles. This paper develops several expressions for the first law, second law and exergy efficiency definitions for the combined cycle based on existing definitions in the literature. Some of the developed equations have been recommended for use over others, depending on the comparison being made. Finally, some of these definitions have been applied to the cycle and the performance of the cycle optimized for maximum efficiency. A Generalized Reduced Gradient (GRG) method was used to perform the optimization. The results of these optimizations are presented and discussed.

On Evaluating Efficiency of a Combined Power and Cooling Cycle

A system for disinfecting a fluid containing microorganisms or chemical contaminants includes a plurality of photocatalyst surfaces secured to a solid surface upon which a fluid to be disinfected contacts. A structure for removing a portion of the photogenerated electrons is in electrical contact with the photocatalyst layer, wherein an electron-hole recombination rate involving the photogenerated electrons and holes is reduced, thus increasing the removal rate of microorganisms or chemical contaminants from the fluid. The system can include a source of photons having a wavelength corresponding to a band gap energy of the photocatalyst to illuminate the photocatalyst layer. The invention can be used in air supply registers of a heating, ventilating and air conditioning system, or in air ducts, or used to disinfect wall coverings, floor coverings, envelopes, packages, and clothing articles.

Photoelectrochemical air disinfection

Water in well-mixed ponds containing photosynthetic algae has been observed to have an extremely high Dissolved Oxygen (DO) content. Up to four times saturation levels of DO have been recorded. Since DO is known to have an important role in the photocatalytic oxidation of organic contaminants in water, it was hypothesized that a faster rate of contaminant destruction would be observed in water drawn from algae ponds supersaturated with DO. In order to verify this hypothesis a bench scale, batch type photoreactor was constructed. Some baseline tests were performed to investigate the influence of UV intensity, water pH and DO content on the photocatalytic destruction of toluene in water. An array of ultraviolet “blacklight” lamps in a lamp box was used to simulate solar ultraviolet radiation. First-order reaction rate constants were calculated from the destruction data, using a kinetic model proposed earlier. The reaction was found to proceed forward equally fast at pH 4 and 10. A power law relation was derived for the reaction rate dependence on UV intensity. Presence of DO in the water was found to be required for the reaction to go forward. Water from an algae pond, supersaturated with dissolved oxygen was spiked with toluene and destruction tests were then conducted in the same reactor. These tests did not show the expected improvement in destruction rates.Copyright © 2002 by ASME

Photocatalytic Oxidation of Toluene in Water From an Algae Pond With High Dissolved Oxygen Content

A new thermodynamic cycle has been developed for the simultaneous production of power and cooling from low temperature heat sources. The proposed cycle combines the Rankine and absorption refrigeration cycles, providing power and cooling in desired ratios to best suit the application. A binary mixture of ammonia and water is used as the working fluid, providing a good thermal match with the sensible heat source over a range of boiling temperatures. Due to its low boiling point, the ammonia-rich vapor expands to refrigeration temperatures while work is extracted through the turbine. Absorption condensation of the vapor back into the bulk solution occurs near ambient temperatures. The proposed cycle is suitable as a bottoming cycle using waste heat from conventional power generation systems, or can utilize low temperature solar or geothermal renewable resources. The cycle can be scaled to residential, commercial or industrial uses, providing power as the primary goal while satisfying some of the cooling requirements of the application. The cycle is under both theoretical and experimental investigations. Initial parametric studies of how the cycle performs at various operating conditions showed the potential for the cycle to be optimized. Optimization studies performed over a range of heat source and heat sink temperatures showed that the cycle could be optimized for maximum work or cooling output, or for first or second law efficiencies. Depending on the heat source temperatures, as much as half of the output may be obtained as refrigeration under optimized conditions, with refrigeration temperatures as low as 205 K being achievable. Maximum second law efficiencies over 60% have been found with the heat source between 350 and 450 K. An experimental system was constructed to verify the theoretical results and to demonstrate the feasibility of the cycle. The investigation focused on the vapor generation and absorption processes, setting up for the power and refrigeration studies to come later. The turbine was simulated with an equivalent expansion process in this initial phase of testing. Results showed that the vapor generation and absorption processes work experimentally, over a range of operating conditions and in simulating the sources and sinks of interest. The potential for combined work and cooling output was evidenced in operating the system. Comparison to ideally simulated results verified that there are thermal and flow losses present, which were assessed to make both improvements in the experimental system and modifications in the simulations to include realistic losses.Copyright © 2003 by ASME

A New Combined Power and Cooling Cycle for Low Temperature Heat Sources

Experiments in photocatalysis often involve the use of blacklight UV lamps to simulate the solar UV spectrum under indoor laboratory conditions. solar UV radiometers (such as the Eppley TUVR) which are calibrated for solar UV spectrum require correction when used to measure the energy from a lamp array. This paper describes a transfer calibration procedure that was used to determine instrument response to the blacklight lamp energy spectrum. It also shows theoretically and experimentally that a correction factor of about 1.15 is needed to use a solar UV radiometer for measurements of outputs from the lamps.

D. Y. Goswami

Papers

On Evaluating Efficiency of a Combined Power and Cooling Cycle

Photoelectrochemical air disinfection

Photocatalytic Oxidation of Toluene in Water From an Algae Pond With High Dissolved Oxygen Content

A New Combined Power and Cooling Cycle for Low Temperature Heat Sources

On the Calibration of a Solar UV Radiometer to Measure Broadband UV Radiation from Blacklight Lamps