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Daniel Pérez de las Vacas
Researcher at Spanish National Research Council
Publications - 1
Citations - 14
Daniel Pérez de las Vacas is an academic researcher from Spanish National Research Council. The author has contributed to research in topics: Allylic rearrangement & Hydride. The author has an hindex of 1, co-authored 1 publications receiving 13 citations.
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Formation and reactivity of new Nicholas–Ferrier pyranosidic cations: novel access to oxepanes via a 1,6-hydride shift/cyclization sequence
TL;DR: Pyranosidic allylic cations that share dicobalt hexacarbonyl propargyl (Nicholas) stabilization at C-1 display a remarkable reactivity leading to either substituted oxepanes or 3-C-branched pyranosides, depending on the substituent at O-6.