The calculation of rate coefficients is a discipline of nonlinear science of importance to much of physics, chemistry, engineering, and biology. Fifty years after Kramers' seminal paper on thermally activated barrier crossing, the authors report, extend, and interpret much of our current understanding relating to theories of noise-activated escape, for which many of the notable contributions are originating from the communities both of physics and of physical chemistry. Theoretical as well as numerical approaches are discussed for single- and many-dimensional metastable systems (including fields) in gases and condensed phases. The role of many-dimensional transition-state theory is contrasted with Kramers' reaction-rate theory for moderate-to-strong friction; the authors emphasize the physical situation and the close connection between unimolecular rate theory and Kramers' work for weakly damped systems. The rate theory accounting for memory friction is presented, together with a unifying theoretical approach which covers the whole regime of weak-to-moderate-to-strong friction on the same basis (turnover theory). The peculiarities of noise-activated escape in a variety of physically different metastable potential configurations is elucidated in terms of the mean-first-passage-time technique. Moreover, the role and the complexity of escape in driven systems exhibiting possibly multiple, metastable stationary nonequilibrium states is identified. At lower temperatures, quantum tunneling effects start to dominate the rate mechanism. The early quantum approaches as well as the latest quantum versions of Kramers' theory are discussed, thereby providing a description of dissipative escape events at all temperatures. In addition, an attempt is made to discuss prominent experimental work as it relates to Kramers' reaction-rate theory and to indicate the most important areas for future research in theory and experiment.

Reaction-rate theory: fifty years after Kramers

The phenomenon of Bose-Einstein condensation of dilute gases in traps is reviewed from a theoretical perspective. Mean-field theory provides a framework to understand the main features of the condensation and the role of interactions between particles. Various properties of these systems are discussed, including the density profiles and the energy of the ground-state configurations, the collective oscillations and the dynamics of the expansion, the condensate fraction and the thermodynamic functions. The thermodynamic limit exhibits a scaling behavior in the relevant length and energy scales. Despite the dilute nature of the gases, interactions profoundly modify the static as well as the dynamic properties of the system; the predictions of mean-field theory are in excellent agreement with available experimental results. Effects of superfluidity including the existence of quantized vortices and the reduction of the moment of inertia are discussed, as well as the consequences of coherence such as the Josephson effect and interference phenomena. The review also assesses the accuracy and limitations of the mean-field approach.

https://arxiv.org/pdf/cond-mat/9806038.pdf

Theory of Bose-Einstein condensation in trapped gases

IN two previous notes1, Prof. Max Born and I have shown that one can obtain a theory of superconductivity by taking account of the fact that the interaction of the electrons with the ionic lattice is appreciable only near the boundaries of Brillouin zones, and particularly strong near the corners of these. This leads to the criterion that the metal should be superconductive if a set of corners of a Brillouin zone is lying very near the Fermi surface, considered as a sphere, which limits the region in the momentum space completely filled with electrons.

On the theory of superconductivity

The authors review the present status of self-consistent mean-field (SCMF) models for describing nuclear structure and low-energy dynamics. These models are presented as effective energy-density functionals. The three most widely used variants of SCMF's based on a Skyrme energy functional, a Gogny force, and a relativistic mean-field Lagrangian are considered side by side. The crucial role of the treatment of pairing correlations is pointed out in each case. The authors discuss other related nuclear structure models and present several extensions beyond the mean-field model which are currently used. Phenomenological adjustment of the model parameters is discussed in detail. The performance quality of the SCMF model is demonstrated for a broad range of typical applications.

Self-consistent mean-field models for nuclear structure

Random-matrix theories in quantum physics : common concepts

Hartree-Fock calculations for spherical nuclei using Skyrme's density-dependent effective nucleon-nucleon interaction are discussed systematically. Skyrme's interaction is described and the general formula for the mean energy of a spherical nucleus derived. Hartree-Fock equations are obtained by varying the mean energy with respect to the single-particle wave functions of occupied states. Relations between the parameters of the Skyrme force and various general properties of nuclear matter and finite nuclei are analyzed. Calculations have been made for closed-shell nuclei using two rather different sets of parameters, both of which give good binding energies and radii for $^{16}\mathrm{O}$ and $^{208}\mathrm{Pb}$. Both interactions give good binding energies and charge radii for all closed-shell nuclei. Calculated electron scattering angular distributions agree qualitatively with experiment, and for one interaction there is good quantitative agreement. The single-particle energies calculated with the two interactions are somewhat different owing to a different nonlocality of the Hartree-Fock potentials, but both interactions give the correct order and density of single-particle levels near the Fermi level. They differ most strongly in their predictions for the energies of $1s$ single-particle states.

David M. Brink

Papers

Hartree-Fock Calculations with Skyrme's Interaction. I. Spherical Nuclei

Effective interactions for Hartree-Fock calculations

Time-dependent hartree-fock theory with Skyrme's interaction

Hartree-Fock calculations with Skyrme's interaction

Kinematical effects in heavy-ion reactions