Many products used in everyday life are made with the assistance of nanotechnologies. Cosmetic, pharmaceuticals, sunscreen, powdered food are only few examples of end products containing nano-sized particles (NPs), generally added to improve the product quality. To evaluate correctly benefits versus risks of engineered nanomaterials and consequently to legislate in favor of consumer’s protection, it is necessary to know the hazards connected with the exposure levels. This information implies transversal studies and a number of different competences. On analytical point of view the identification, quantification and characterization of NPs in food matrices and in cosmetic or personal care products pose significant challenges, because NPs are usually present at low concentration levels and the matrices, in which they are dispersed, are complexes and often incompatible with analytical instruments that would be required for their detection and characterization. This paper focused on some analytical techniques suitable for the detection, characterization and quantification of NPs in food and cosmetics products, reports their recent application in characterizing specific metal and metal-oxide NPs in these two important industrial and market sectors. The need of a characterization of the NPs as much as possible complete, matching complementary information about different metrics, possible achieved through validate procedures, is what clearly emerges from this research. More work should be done to produce standardized materials and to set-up methodologies to determine number-based size distributions and to get quantitative date about the NPs in such a complex matrices.

/pdf/nanomaterials-in-consumer-products-a-challenging-analytical-1amc37d8d4.pdf

Nanomaterials in consumer products: a challenging analytical problem.

Mutagenicity evaluation of metal oxide nanoparticles by the bacterial reverse mutation assay

Immunotoxicology of non-functionalized engineered nanoparticles in aquatic organisms with special emphasis on fish--review of current knowledge, gap identification, and call for further research.

A new method for determining the size of titanium dioxide particles is proposed and assayed in a commercial sunscreen product. Today many sun protection cosmetics incorporate physical UV filters as active ingredients, and there are no official methods for determining these compounds in sunscreen cosmetics. Here flow field-flow fractionation (FlFFF) has been tested, first to sort two different types of TiO2 nano- and microstandard materials (AeroxideTiO2 Degussa P-25 and TiO2 rutile 0.1−0.2-μm size) and then to fractionate TiO2 particles, extracted from a commercial sunscreen lotion. All the TiO2 FlFFF separations were detected by UV but during elution fractions were collected and their Ti content measured by inductively coupled plasma-atomic emission spectrometer (ICP-AES); the Ti concentration profiles obtained by ICP-AES were well correlated with the UV signals. The TiO2 particle mass-size distribution were calculated from the UV profiles. This methodology is relatively simple and rapid, and the sample ...

TiO2 in Commercial Sunscreen Lotion: Flow Field-Flow Fractionation and ICP-AES Together for Size Analysis

Effects of nanosized titanium dioxide on innate immune system of fathead minnow (Pimephales promelas Rafinesque, 1820).

Titanium dioxide determination in sunscreen by energy dispersive X-ray fluorescence methodology.

http://www.latamjpharm.org/trabajos/27/5/LAJOP_27_5_1_3_A10I17I8E8.pdf

Fluorescência De Raios X Por Dispersão De Energia Aplicada No Controle De Qualidade De Protetor Solar

/pdf/determination-of-inorganic-elements-in-sunscreen-by-using-2wlrh48s7v.pdf

Diego de Dio Ferreira

Papers

Titanium dioxide determination in sunscreen by energy dispersive X-ray fluorescence methodology.

Fluorescência De Raios X Por Dispersão De Energia Aplicada No Controle De Qualidade De Protetor Solar

Determination of inorganic elements in sunscreen by using energy dispersive x-ray fluorescence

Total Reflection X-ray Fluorescence spectrometry determination of titanium dioxide released from UV-protective textiles during wash.