E
E. D. Lubuzh
Researcher at Russian Academy of Sciences
Publications - 29
Citations - 17
E. D. Lubuzh is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Enantioselective synthesis & Infrared spectroscopy. The author has an hindex of 2, co-authored 29 publications receiving 17 citations.
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Formal synthesis of strobilurins A and X
TL;DR: In this article, the precursors of strobilurins A and X were synthesized by highly stereospecific reactions from 2-(2-tert-butyldimethylsilyloxyethyl)- and 2-[2-(4-methoxybenzyloxy)-ethyl]-5-arylpenta-2E,4E-dien-1-ols.
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Asymmetric aminoacid synthesis by catalytic reduction of azlactones of substituted acylaminoacrylic acids Communication 17. Reaction of PdCl2 with S-(-)-α-phenylmethylamine under reducing conditions
E. I. Karpeiskaya,L. F. Godunova,E. S. Levitina,M. R. Lyubeznova,E. I. Klabunovskii,E. D. Lubuzh,A. I. Lutsenko +6 more
TL;DR: When PdCl2 is reduced by hydrogen in the presence of S-(-)-α-phenylethylamine in chloroform, zero-valent complexes of Pd with S-( −)-α -phenylethlamine are formed as discussed by the authors, which are enantioselective catalysts for reductive aminolysis of the azlactones of dehydroacyl-aminoacids.
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Organosilicon compounds having hydrocarbon bridges between silicon atoms
TL;DR: In this paper, the structure of the fundamental structural unit was established for catalytic polycondensation products obtained from α,ω-bistrimethylsilylalkanes and also for polymers obtained by the thermal polymerization of 1,1-dimethylsilacyclobutane and the catalytic polymerisation of 1.1.
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Quantum-chemical and spectroscopic studies of structures of 1 : 2 complexes of carbonyl compounds with aluminum halides
TL;DR: In this paper, the 1 : 1 and 1 : 2 complexes of benzophenone with AlBr3 were analyzed, and the differences in the low frequency regions of these spectra, which are indicative of the presence of the Br2Al-Br-AlBr3 fragment in the 1: 2 complex, were discussed.
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Free-radical addition of alcohols toα, β-unsaturated ketones and tautomerism of formed 4-hydroxyketones
TL;DR: According to the data of the IR spectra, the 4-hydroxy ketones exist in both the open and cyclic (hemiacetal) forms as discussed by the authors, the amount of the open form increases with increase in the steric hindrance in the cyclization step.