E
Eamonn F. Healy
Researcher at St. Edward's University
Publications - 52
Citations - 13473
Eamonn F. Healy is an academic researcher from St. Edward's University. The author has contributed to research in topics: MNDO & Active site. The author has an hindex of 15, co-authored 50 publications receiving 13197 citations. Previous affiliations of Eamonn F. Healy include University of Texas at Austin.
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An Unusually Large Secondary Deuterium Isotope Effect. Thermal Trans-Cis Isomerization of trans-1-Phenylcyclohexene
TL;DR: The magnitudes of secondary deuterium isotope effects (SDIE) are generally in the range of 0.9 − 1.25 as discussed by the authors, and are often satisfactorily rationalized by the zero point energy (ZPE) change on going from reactant to transition state due to C-H rehybridization.
Journal ArticleDOI
Organic chemistry as representation
TL;DR: Reforming organic mechanisms to include single electron transfer (SET) as a component of, or an alternative to, the prevailing iconic descriptions can provide for a more empirically adequate mechanistic description.