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Showing papers by "Eberhardt Herdtweck published in 1990"


Journal ArticleDOI
TL;DR: In this article, the reaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes.

25 citations


Journal ArticleDOI
TL;DR: L'alkylation de (η 5 -C 5 Me 5 )Re(=O)(Cl)(CH 3 ) avec R'MgCl [R'=C 2 H 5, CH 2 Si(CH 3 ), 3, CH 2 C(CH3 ) 3 ] donne les complexes (δ 5 -c 5 Me5 ) Re(= O)(CH3 ),(R'). Les complexes ( Δ 5 - c 5 Me five )Re((O)(R' 2 ) subissent des reactions d'halogenation avec (

18 citations


Journal ArticleDOI
TL;DR: In this paper, a bimetallic mechanism, in which HSCH 2 COOR is added to the MM triple bond thus forming a six-membered ring intermediate, is proposed.

8 citations