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Principles Of Fluorescence Spectroscopy

Functional π-Gelators and Their Applications

Over the past few years, there has been a great deal of interest in the development of hydrogel materials with tunable structural, mechanical, and rheological properties, which exhibit rapid and autonomous self-healing and self-recovery for utilization in a broad range of applications, from soft robotics to tissue engineering. However, self-healing hydrogels generally either possess mechanically robust or rapid self-healing properties but not both. Hence, the development of a mechanically robust hydrogel material with autonomous self-healing on the time scale of seconds is yet to be fully realized. Here, the current advances in the development of autonomous self-healing hydrogels are reviewed. Specifically, methods to test self-healing efficiencies and recoveries, mechanisms of autonomous self-healing, and mechanically robust hydrogels are presented. The trends indicate that hydrogels that self-heal better also achieve self-healing faster, as compared to gels that only partially self-heal. Recommendations to guide future development of self-healing hydrogels are offered and the potential relevance of self-healing hydrogels to the exciting research areas of 3D/4D printing, soft robotics, and assisted health technologies is highlighted.

Self-Healing Hydrogels

Detection Ying Zhou,†,‡ Jun Feng Zhang, and Juyoung Yoon*,† †Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea ‡Key Laboratory of Medicinal Chemistry for Natural Resource, School of Chemical Science and Technology, Yunnan University, Kunming, 650091, P. R. China College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, P. R. China

Fluorescence and colorimetric chemosensors for fluoride-ion detection.

Fogging occurs when moisture condensation takes the form of accumulated droplets with diameters larger than 190 nm or half of the shortest wavelength (380 nm) of visible light. This problem may be effectively addressed by changing the affinity of a material’s surface for water, which can be accomplished via two approaches: i) the superhydrophilic approach, with a water contact angle (CA) less than 5°, and ii) the superhydrophobic approach, with a water CA greater than 150°, and extremely low CA hysteresis. To date, all techniques reported belong to the former category, as they are intended for applications in optical transparent coatings. A well-known example is the use of photocatalytic TiO2 nanoparticle coatings that become superhydrophilic under UV irradiation. Very recently, a capillary effect was skillfully adopted to achieve superhydrophilic properties by constructing 3D nanoporous structures from layer-by-layer assembled nanoparticles. The key to these two “wet”-style antifogging strategies is for micrometer-sized fog drops to rapidly spread into a uniform thin film, which can prevent light scattering and reflection from nucleated droplets. Optical transparency is not an intrinsic property of antifogging coatings even though recently developed antifogging coatings are almost transparent, and the transparency could be achieved by further tuning the nanoparticle size and film thickness. To our knowledge, the antifogging coatings may also be applied to many fields that do not require optical transparency, including, for example, paints for inhibiting swelling and peeling issues and metal surfaces for preventing corrosion. These types of issues, which are caused by adsorption of moisture, are hard to solve by the superhydrophilic approach because of its inherently “wet” nature. Thus, a “dry”-style antifogging strategy, which consists of a novel superhydrophobic technique that can prevent moisture or microscale fog drops from nucleating on a surface, is desired. Recent bionic researches have revealed that the self-cleaning ability of lotus leaves and the striking ability of a water-strider’s legs to walk on water can be attributed to the ideal superhydrophobicity of their surfaces, induced by special microand nanostructures. To date, the biomimetic fabrication of superhydrophobic microand/or nanostructures has attracted considerable interest, and these types of materials can be used for such applications as self-cleaning coatings and stain-resistant textiles. Although a superhydrophobic technique inspired by lotus leaves is expected to be able to solve such fogging problems because the water droplets can not remain on the surface, there are no reports of such antifogging coatings. Very recently, researchers from General Motors have reported that the surfaces of lotus leaves become wet with moisture because the size of the fog drops are at the microscale—so small that they can be easily trapped in the interspaces among micropapillae. Thus, lotuslike surface microstructures are unsuitable for superhydrophobic antifogging coatings, and a new inspiration from nature is desired for solving this problem. In this communication, we report a novel, biological, superhydrophobic antifogging strategy. It was found that the compound eyes of the mosquito C. pipiens possess ideal superhydrophobic properties that provide an effective protective mechanism for maintaining clear vision in a humid habitat. Our research indicates that this unique property is attributed to the smart design of elaborate microand nanostructures: hexagonally non-close-packed (ncp) nipples at the nanoscale prevent microscale fog drops from condensing on the ommatidia surface, and hexagonally close-packed (hcp) ommatidia at the microscale could efficiently prevent fog drops from being trapped in the voids between the ommatidia. We also fabricated artificial compound eyes by using soft lithography and investigated the effects of microand nanostructures on the surface hydrophobicity. These findings could be used to develop novel superhydrophobic antifogging coatings in the near future. It is known that mosquitoes possess excellent vision, which they exploit to locate various resources such as mates, hosts, and resting sites in a watery and dim habitat. To better understand such remarkable abilities, we first investigated the interaction between moisture and the eye surface. An ultrasonic humidifier was used to regulate the relative humidity of the atmosphere and mimic a mist composed of numerous tiny water droplets with diameters less than 10 lm. As the fog was C O M M U N IC A IO N

The dry-style antifogging properties of mosquito compound eyes and artificial analogues prepared by soft lithography: a superhydrophobic state with high adhesive force

Insights into the Formations of Host–Guest Complexes Based on the Benzimidazolium Based Ionic Liquids−β-Cyclodextrin Systems

We describe a fast, efficient, and mild approach to prepare chemically reduced graphene oxide (rGO) at room temperature using divalent europium triflate {Eu(OTf)2}. The characterization of solution-processable reduced graphene oxide has been carried out by various spectroscopic (FT-IR, UV–visible absorption, and Raman), microscopic (TEM and AFM), and powder X-ray diffraction (XRD) techniques. Kinetic study indicates that the bimolecular rate constants for the reduction of graphene oxide are 13.7 ± 0.7 and 5.3 ± 0.1 M–1 s–1 in tetrahydrofuran (THF)–water and acetonitrile (ACN)–water mixtures, respectively. The reduction rate constants are two orders of magnitude higher compared to the values obtained in the case of commonly used reducing agents such as the hydrazine derivative, sodium borohydride, and a glucose–ammonia mixture. The present work introduces a feasible reduction process for preparing reduced graphene oxide at ambient conditions, which is important for bulk production of GO. More importantly, ...

Rate and Mechanistic Investigation of Eu(OTf)2-Mediated Reduction of Graphene Oxide at Room Temperature

The present work reports an easy-to-make procedure of Janus dendrimers containing two most widely used dendrons [poly(aryl ether) and poly(amido amine) {PAMAM}], and utilize them, for the first time, to form a hydrogel with supergelation ability The first generation (G1G1) Janus dendrimer forms hydrogel with a critical gelation concentration (CGC) of 65 mg/mL, whereas the CGC for G1G15 dendrimer went as low as 090 mg/mL in DMSO-H2O mixture Judicious choice of solvent medium (ethanol-water) led to the formation of flexible morphology (long fibres to vesicles) by the Janus dendrimers, suggesting the possibility of tuning the mechanism of self-assembly in the system The dye (rhodamine B) loading efficiency in the gel was successfully carried out using different generations {G1G1 and G1G15} of the Janus dendrimer Generation G1G1 hydrogel (1 wt%) showed maximum dye loading efficiency of 4 mg/mL Rhodamine B release profiles from the Janus dendrimers were determined and the results indicate that slow release kinetics was observed in the case of G1G1, where the self-assembly is robust

Janus Dendrimer from Poly(Aryl Ether) Linked PAMAM for Supergelation and Guest Release

Chimie douce hydrogen production from Hg contaminated water, with desirable throughput, and simultaneous Hg-removal

Developing composite hydrogels with excellent self-healing ability and reasonable mechanical strength is extremely challenging. Herein, to overcome this difficulty, we identify the importance of balancing the ratio between the components of a composite hydrogel based on graphene oxide and poly(acrylic acid-acrylamide) [GOxAAM]. The gel exhibits enhanced mechanical strength, excellent self-healing ability, and extraordinary swelling capacity (a swelling ratio of 732) at room temperature and neutral pH. Further, the dye adsorption of the composite hydrogel has been investigated. The hydrogel could selectively adsorb organic cationic dyes (methylene blue vs. rhodamine B) from contaminated water with remarkable efficiency (90-95%). The kinetics investigation suggests that the dye adsorption on this composite hydrogel follows a pseudo-second-order model. The reusability of the hydrogel has been demonstrated by repeating the adsorption-desorption process over 10-14 cycles with almost identical results in the adsorption efficiency. Moreover, the hydrogel is utilized as a solvent-induced slow release source for graphene quantum dots (GQDs). The results taken together suggest that the (GOxAAM) composite gel can be a promising candidate for developing multifunctional gel materials.

Edamana Prasad

Papers

Insights into the Formations of Host–Guest Complexes Based on the Benzimidazolium Based Ionic Liquids−β-Cyclodextrin Systems

Rate and Mechanistic Investigation of Eu(OTf)2-Mediated Reduction of Graphene Oxide at Room Temperature

Janus Dendrimer from Poly(Aryl Ether) Linked PAMAM for Supergelation and Guest Release

Chimie douce hydrogen production from Hg contaminated water, with desirable throughput, and simultaneous Hg-removal

Self-healing stable polymer hydrogel for pH regulated selective adsorption of dye and slow release of graphene quantum dots