Showing papers by "Edward A. Boyle published in 1983"

Trace Metals in Sea Water

Abstract: Session I: Metalloids and the Hydride Generation.- The Determination of the Chemical Species of Some of the "Hydride Elements" (Arsenic, Antimony, Tin, and Germanium) in Sea Water: Methodology and Results.- Antimony Content and Speciation in the Water Column and Interstitial Waters of Saanich Inlet.- Ultratrace Speciation and Biogenesis of Methyltin Transport Species in Estuarine Waters.- The Relationship of the Distribution of Dissolved Selenium IV and VI in Three Oceans to Physical and Biological Processes.- Session II: Arctic Chemistry.- Trace Metals in the Arctic Ocean.- Copper in Sub-Arctic Waters of the Pacific Northwest.- Low Level Determination of Trace Metals in Arctic Sea Water and Snow by Differential Pulse Anodic Stripping Voltammetry.- The Relationship between Distributions of Dissolved Cadmium, Iron, and Aluminium and Hydrography in the Central Arctic Ocean.- Session III: Intercalibration Exercise.- Intercomparison of Seawater Sampling Devices for Trace Metals.- The Analysis of Trace Metals in Biological Reference Materials: A Discussion of the Results of the Intercomparison Studies Conducted by the International Council for the Exploration of the Sea.- An Intercomparison of Sampling Devices and Analytical Techniques Using Sea Water from a CEPEX Enclosure.- Session IV: Estuarine Processes Involving Metals.- Role of Fresh Water/Sea Water Mixing on Trace Metal Adsorption Phenomena.- Effects of Particle Size and Density on the Transport of Metals to the Oceans.- The Effect of Sewage Effluents on the Flocculation of Major and Trace Elements in a Stratified Estuary.- Impoverishment and Decrease of Metallic Elements Associated with Suspended Matter in the Gironde Estuary.- The Significance of the River Input of Chemical Elements to the Ocean.- Session V: Air/Sea Exchange and Coastal Processes Involving Metals.- Air-Sea Exchange of Mercury.- Separation of Copper and Nickel by Low Temperature Processes.- The Fate of Particles and Particle-Reactive Trace Metals in Coastal Waters: Radioisotope Studies in Microcosms.- Trace Metals in a Landlocked Intermittently Anoxic Basin.- Session VI: Ocean Distribution and Analysis.- Thorium Isotope Distributions in the Eastern Equatorial Pacific.- Aspects of the Surface Distributions of Copper, Nickel, Cadmium, and Lead in the North Atlantic and North Pacific.- Mn, Ni, Cu, Zn, and Cd in the Western North Atlantic.- Some Recent Measurements of Trace Metals in Atlantic Ocean Waters.- Determination of the Rare Earth Elements in Sea Water.- The Cycle of Living and Dead Particulate Organic Matter in the Pelagic Environment in Relation to Trace Metals.- Trace Metal Levels in Sea Water from the Skagerrak and the Kattegat.- Mercury Concentrations in the North Atlantic in Relation to Cadmium, Aluminium and Oceanographic Parameters.- Perturbations of the Natural Lead Depth Profile in the Sargasso Sea by Industrial Lead.- Copper, Nickel and Cadmium in the Surface Waters of the Mediterranean.- Accurate and Precise Analysis of Trace Levels of Cu, Cd, Pb, Zn, Fe and Ni in Sea Water by Isotope Dilution Mass Spectrometry.- Session VII: Chemical Speciation.- Studies of the Chemical Forms of Trace Elements in Sea Water Using Radiotracers.- Trace Metals (Fe, Cu, Zn, Cd) in Anoxic Environments.- The Behavior of Trace Metals in Marine Anoxic Waters: Solubilities at the Oxygen-Hydrogen Sulfide Interface.- Variations of Dissolved Organic Copper in Marine Waters.- Trace Metals Speciation in Nearshore Anoxic and Suboxic Pore Waters.- The Contrasting Geochemistry of Manganese and Chromium in the Eastern Tropical Pacific Ocean.- Potentialities and Applications of Voltammetry in Chemical Speciation of Trace Metals in the Sea.- Studies of Cadmium, Copper and Zinc Interactions with Marine Fulvic and Humic Materials in Seawater Using Anodic Stripping Voltammetry.- Chemical Periodicity and the Speciation and Cycling of the Elements.- Potentiometric and Conformational Studies of the Acid-Base Properties of Fulvic Acid from Natural Waters.- Copper Speciation in Marine Waters.- Session VIII: Metals and the Biosphere.- Plankton Compositions and Trace Element Fluxes from the Surface Ocean.- Metals in Seawater as Recorded by Mussels.- Trace Elements and Primary Production: Problems, Effects and Solutions.- Trace Metals and Plankton in the Oceans: Facts and Speculations.- Sensitivity of Natural Bacterial Communities to Additions of Copper and to Cupric Ion Activity: A Bioassay of Copper Complexation in Seawater.- List of Participants.- Index of Authors.

Chemical accumulation variations under the Peru Current during the past 130,000 years

Abstract: The titanium to aluminum ratio in core V19–29 is correlated with aluminosilicate accumulation rates. This correlation may be due to Pleistocene eolian transport fluctuations which alter the mean grain size of sedimented eolian material. The relation between aluminum accumulation rate and Ti/Al, established from accumulation rates integrated over 11,000–50,000 year intervals, can be inverted to compute a high-resolution record of aluminosilicate and calcium carbonate accumulation rates over the past 130,000 years. Carbonate accumulation rates are closely related to the oxygen isotope record in the core, with a phase lag and damping constant that is compatible with the response time (shown to be only 6000 years) of calcium carbonate in the ocean. Carbonate sedimentation at this site responds to several processes independently correlated with climatic change. The relative importance of these processes for carbonate sedimentation at this site can be constrained by the record in this core and other lines of evidence: 15% of the increased carbonate deposition at this site during glacial periods may be due to diminished NADW (North Atlantic deep water) formation; 10% is due to carbonate productivity decreases in the North Atlantic; 25% may be due to a diminished shallow-sea carbonate sink; and the residual 50% must be due to a local productivity increase. These assignments are consistent with observations on carbonate paleoceanography in the North Atlantic. Aluminosilicate accumulation rate variations correlate with the record of eolian quartz deposition near northwest Africa and, in a general way, with the climatic record. But in detail the record differs substantially from the oxygen isotope record and may provide independent evidence on the nature of climate dynamics.

Copper, Nickel and Cadmium in the Surface Waters of the Mediterranean

Abstract: Copper, nickel, and cadmium have been determined on 50 surface samples throughout the Mediterranean All of these elements are substantially more concentrated in the surface waters of the Mediterranean than in similar nutrient-depleted waters in the open ocean A mass-balance model for the Mediterranean allows limits to be placed on the magnitudes of the trace element sources The actual source or sources cannot be resolved from the data, and it is not clear whether this trace element enrichment is natural or anthropogenic in origin

Aspects of the Surface Distributions of Copper, Nickel, Cadmium, and Lead in the North Atlantic and North Pacific

Abstract: The concentrations of copper, nickel, and cadmium have been determined on over 400 surface samples; 10 samples were also analyzed for lead. Nickel and cadmium are closely associated with nutrient distributions, being low (about 2 nmol kg−1 for Ni and less than 20 pmol kg−1 for Cd) in the central gyres and elevated to 3–3.5 nmol kg−1 (Ni) and 40–80 pmol kg−1 (Cd) in the equatorial eastern Pacific and in the cool eastern boundary currents. There are large regional variations in their element-nutrient correlations, however. Copper is slightly elevated in cool eastern boundary waters (1.3 nmol kg−1) relative to North Pacific and South Atlantic central gyres, but the Sargasso Sea has higher copper concentrations (1.4 nmol kg−1) than the other central gyres. Copper concentrations in coastal waters of the Gulf of Panama are elevated to 3–4 nmol kg−1; this coastal water advects seaward and creates ‘events’ of high — Cu waters in the oceanic interior. Lead concentrations in the North Atlantic (100–250 pmol kg−1) are higher than in the North Pacific.