Solid-state electrolytes (SSEs) have emerged as high-priority materials for safe, energy-dense and reversible storage of electrochemical energy in batteries. In this Review, we assess recent progress in the design, synthesis and analysis of SSEs, and identify key failure modes, performance limitations and design concepts for creating SSEs to meet requirements for practical applications. We provide an overview of the development and characteristics of SSEs, followed by analysis of ion transport in the bulk and at interfaces based on different single-valent (Li+, Na+, K+) and multivalent (Mg2+, Zn2+, Ca2+, Al3+) cation carriers of contemporary interest. We analyse the progress in overcoming issues associated with the poor ionic conductivity and high interfacial resistance of inorganic SSEs and the poor oxidative stability and cation transference numbers of polymer SSEs. Perspectives are provided on the design requirements for future generations of SSEs, with a focus on the chemical, geometric, mechanical, electrochemical and interfacial transport features required to accelerate progress towards practical solid-state batteries in which metals are paired with energetic cathode chemistries, including Ni-rich and Li-rich intercalating materials, sustainable organic materials, S8, O2 and CO2. Solid-state batteries based on electrolytes with low or zero vapour pressure provide a promising path towards safe, energy-dense storage of electrical energy. In this Review, we consider the requirements and design rules for solid-state electrolytes based on inorganics, organic polymers and organic–inorganic hybrids.

Designing solid-state electrolytes for safe, energy-dense batteries

The present disclosure relates to a semiconductor light emitting device, comprising: a plurality of semiconductor layers, including a first semiconductor layer having a first conductivity, a second semiconductor layer having a second conductivity different from the first conductivity, and an active layer interposed between the first semiconductor layer and the second semiconductor layer, generating light via electron-hole recombination; a first electrode, supplying either electrons or holes to the plurality of semiconductor layers; a second electrode, supplying, to the plurality of semiconductor layers, electrons if the holes are supplied by the first electrode, or holes if the electrons are supplied by the first electrode; a non-conductive distributed bragg reflector coupled to the plurality of semiconductor layers, reflecting the light from the active layer; and a first light-transmitting film coupled to the distributed bragg reflector from a side opposite to the plurality of semiconductor layers with respect to the non-conductive distributed bragg reflector, with the first light-transmitting film having a refractive index lower than an effective refractive index of the distributed bragg reflector.

Semiconductor Light Emitting Device

The invention provides an anode capable of relaxing stress due to expansion and shrinkage of an anode active material layer associated with charge and discharge, or an anode capable of reducing structural destruction of the anode active material layer and reactivity between the anode active material layer and an electrolyte associated with charge and discharge, and a battery using it. The anode active material layer contains an element capable of forming an alloy with Li, for example, at least one from the group consisting of simple substances, alloys, and compounds of Si or Ge. An interlayer containing a material having superelasticity or shape-memory effect is provided between an anode current collector and the anode active material layer. Otherwise, the anode current collector is made of the material having superelasticity or shape-memory effect. Otherwise, a thin film layer containing the material having superelasticity or shape-memory effect is formed on the anode active material layer.

Anode and battery

A high capacity lithium secondary battery with excellent safety is provided by suppressing expansion of a negative electrode active material during charge and increasing the content of a heat-resistant resin in a separator relative to conventional one. The lithium secondary battery includes: a negative electrode active material that comprises compound particles containing at least one metal element selected from the group consisting of Si, Sn, Al, and Zn; and a separator that has a first porous layer comprising polyolefin and a second porous layer comprising a heat-resistant resin. The separator contains 10 to 60 parts by weight of the second porous layer per 100 parts by weight of the first porous layer.

Lithium Secondary Battery

An outer insulation member made of a first resin packs a part of an anode terminal. The packed part of the anode terminal has a predetermined section. All surfaces of the predetermined section consist of a front surface, a back surface and edges connecting between the front surface and the back surface. The front surface includes a connection area. An anode lead wire is connected to the connection area while being not connected to the anode terminal other than the connection area. The all surfaces of the predetermined section are completely covered with a mask layer made of a second resin except for the connection area. The second resin is different from the first resin in at least one of composition thereof, content of an inclusion, size of an inclusion and shape of an inclusion.

Solid electrolytic capacitor

Anodic valve metal foils, roughened and provided with dielectric layers, and collector metal foils (metal foils for collector) are laminated alternately to cross with cathodic electroconductive polymer layers therebetween. Anodic terminals and cathodic terminals are connected with the respective ends of the metal foils. For the anodic valve metal foils, an aluminum foil whose internal is an unroughened bulk metal layer is used. The collector metal foil is selected from the group consisting of an Al foil similar to the anodic valve metal foil, an Ni foil, a Cu foil, and an aluminum foil including carbon. As a result, a four-terminal capacitor to provide high capacitance, low impedance, high current-carrying capacity and less heat generation, as well as low ESR and low ESL, is obtained.

Four-terminal capacitor

A negative electrode for a non-aqueous electrolyte secondary battery including a current collector, and an electrode material layer including an electrode material capable of reversibly absorbing and desorbing Li ions is provided. The electrode material includes at least one element selected from the group consisting of Si, Sn and Al; the surface of the current collector is provided with protrusions; the electrode material layer is disposed on the surfaces of the current collector and the protrusions; and the protrusion has a portion facing the surface of the current collector other than a portion that is brought into contact with the current collector. Thus, a negative electrode for a non-aqueous electrolyte battery having high properties such as an energy density, charging/discharging cycle property, and the like, and a non-aqueous electrolyte secondary battery can be provided.

Battery and non-aqueous electrolyte secondary battery using the same

A conductive paste used for mounting an electronic part on a board or connecting electrodes, a conductive structure using the paste, an electronic part, a module, a circuit board, a method for electrical connection, a method for manufacturing a circuit board, and a method for manufacturing a ceramic electronic part (all will be refered to as 'conductive paste and so forth') are disclosed. Electrical connection using conductive paste is used in various fields for its ease. The conductivity of conductive paste is ensured by the contact between conductive particles in the conductive paste. Conventionally, stress is generated in conductive paste when it is heated, and the contact between conductive particles is partially broken when the stress is relaxed, causing a problem of high resistance. The conductive paste of the invention is characterized in that it contains conductive particles, a foaming material foamable when heated or depressurized, and a resin and it does not lose its conductivity even after the foaming material is foamed. The base has a good stress resistance and enables low-resistance electrical connection.

Conductive paste, conductive structure using the same, electronic part, module, circuit board, method for electrical connection, method for manufacturing circuit board, and method for manufacturing ceramic electronic part

There is provided a solid electrolytic capacitor including an anode body formed of a valve-action metal with a dielectric oxide coating layer formed on its surface, a cathode body, and an electroconductive polymer layer disposed between the anode body and the cathode body. The electroconductive polymer layer contains a softener for softening the electroconductive polymer layer, so that a solid electrolytic capacitor is provided that has small variations in characteristics, a lower equivalent series resistance (ESR), and an excellent high frequency property. In addition, when the anode and cathode of a solid electrolytic capacitor including an electroconductive polymer as a solid electrolyte are joined to each other, a lower ESR can be obtained under a lower pressure, and the electroconductive polymer layer can be prevented from being peeled off.

Solid electrolytic capacitor and method of manufacturing the same

All-solid-state lithium-ion batteries (LIBs) are one of the promising candidates to overcome some issues of conventional LIBs with liquid electrolytes. However, high interfacial resistance of Li-ion transfer at the electrode/solid electrolyte limits their performance. Thus, it is important to clarify interfacial phenomena in a nanometer scale. Here, we present a new method to dynamically observe the Li-ion distribution and Co-ion electronic states in a LiCoO2 cathode of the all-solid-state LIB during charge and discharge reactions using operando scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS). By applying a hyperspectral image analysis of non-negative matrix factorization (NMF) to the STEM-EELS, we succeeded in clearly observing the quantitative Li-ion distribution in the operando condition. We found from the operando observation with NMF that the Li ions did not uniformly extract/insert during the charge/discharge reactions, and the activity of the electroche...

Quantitative Operando Visualization of Electrochemical Reactions and Li Ions in All-Solid-State Batteries by STEM-EELS with Hyperspectral Image Analyses.

Emiko Igaki

Papers

Four-terminal capacitor

Battery and non-aqueous electrolyte secondary battery using the same

Conductive paste, conductive structure using the same, electronic part, module, circuit board, method for electrical connection, method for manufacturing circuit board, and method for manufacturing ceramic electronic part

Solid electrolytic capacitor and method of manufacturing the same

Quantitative Operando Visualization of Electrochemical Reactions and Li Ions in All-Solid-State Batteries by STEM-EELS with Hyperspectral Image Analyses.