Metal-mediated reductive hydrodehalogenation of organic halides.

Recent developments in the chemistry of amine- and phosphine-boranes

B(C6F5)3 catalyzed hydrosilation of enones and silyl enol ethers

Chemical investigation of the EtOAc extract of the endophytic fungus Bionectria ochroleuca, isolated from the inner leaf tissues of the plant Sonneratia caseolaris (Sonneratiaceae) from Hainan island (China), yielded two new peptides, pullularins E and F (1 and 2) together with three known compounds (3–5). The structures of the new compounds were unambiguously determined on the basis of one- and two-dimensional NMR spectroscopy as well as by high-resolution mass spectrometry. The absolute configurations of amino acids were determined by HPLC analysis of acid hydrolysates using Marfey’s method. The isolated compounds exhibited pronounced to moderate cytotoxic activity against the mouse lymphoma cells (L5178Y) with EC50 values ranging between 0.1 and 6.7 µg/mL.

https://www.mdpi.com/1660-3397/10/5/1081/pdf

Pullularins E and F, two new peptides from the endophytic fungus Bionectria ochroleuca isolated from the mangrove plant Sonneratia caseolaris

Direct reductive amination and selective 1,2-reduction of α,β-unsaturated aldehydes and ketones by NaBH4 using H3PW12O40 as catalyst

Aminoborohydrides. 2. Regiospecific reductions of α, β-unsaturated carbonyl compounds with lithium pyrrolidinoborohydride. A facile conversion of α, β-unsaturated aldehydes and ketones to the corresponding allylic alcohols in high purity

Lithium aluminum hydride-N-methylpyrrolidine complex. 1. Synthesis and reactivity of lithium aluminum hydride-N-methyplyrrolidine complex. An air and thermally stable reducing agent derived from lithium aluminum hydride

Lithium Aluminum Hydride‐N‐methylpyrrolidine Complex. Part 1. Synthesis and Reactivity of Lithium Aluminum Hydride‐N‐ methylpyrrolidine Complex. An Air and Thermally Stable Reducing Agent Derived from Lithium Aluminum Hydride.

Aminoborohydrides. Part 2. Regiospecific Reductions of α,β‐ Unsaturated Carbonyl Compounds with Lithium Pyrrolidinoborohydride. A Facile Conversion of α,β‐Unsaturated Aldehydes and Ketones to the Corresponding Allylic Alcohols in High Purity.

Eric L. Stangeland

Papers

Aminoborohydrides. 2. Regiospecific reductions of α, β-unsaturated carbonyl compounds with lithium pyrrolidinoborohydride. A facile conversion of α, β-unsaturated aldehydes and ketones to the corresponding allylic alcohols in high purity

Lithium aluminum hydride-N-methylpyrrolidine complex. 1. Synthesis and reactivity of lithium aluminum hydride-N-methyplyrrolidine complex. An air and thermally stable reducing agent derived from lithium aluminum hydride

Lithium Aluminum Hydride‐N‐methylpyrrolidine Complex. Part 1. Synthesis and Reactivity of Lithium Aluminum Hydride‐N‐ methylpyrrolidine Complex. An Air and Thermally Stable Reducing Agent Derived from Lithium Aluminum Hydride.

Aminoborohydrides. Part 2. Regiospecific Reductions of α,β‐ Unsaturated Carbonyl Compounds with Lithium Pyrrolidinoborohydride. A Facile Conversion of α,β‐Unsaturated Aldehydes and Ketones to the Corresponding Allylic Alcohols in High Purity.