Magnetocaloric materials with a Curie temperature near room temperature have attracted significant interest for some time due to their possible application for high-efficiency refrigeration devices. This review focuses on a number of key issues of relevance for the characterization, performance and implementation of such materials in actual devices. The phenomenology and fundamental thermodynamics of magnetocaloric materials is discussed, as well as the hysteresis behavior often found in first-order materials. A number of theoretical and experimental approaches and their implications are reviewed. The question of how to evaluate the suitability of a given material for use in a magnetocaloric device is covered in some detail, including a critical assessment of a number of common performance metrics. Of particular interest is which non-magnetocaloric properties need to be considered in this connection. An overview of several important materials classes is given before considering the performance of materials in actual devices. Finally, an outlook on further developments is presented.

Materials Challenges for High Performance Magnetocaloric Refrigeration Devices

http://spiral.imperial.ac.uk/bitstream/10044/1/40571/2/TauFactor.pdf

TauFactor: An open-source application for calculating tortuosity factors from tomographic data

https://hal.archives-ouvertes.fr/hal-02594054/document

A review on experience feedback and numerical modeling of packed-bed thermal energy storage systems

A simple model for estimating the emissivity of the surface of a powder bed by knowing only the bed porosity and its solid emissivity is presented. Estimates by the model are compared with experimental measurements for powder beds of alumina, silicon carbide, and iron. Agreement within the uncertainty of the measurements of ±10% is obtained. A view factor that adopts the predicted emissivity of the powder beds into its term is suggested for the calculation of the conductivity by radiation. For the prediction of the thermal conductivity of the powder beds, the authors compared the existing models in literature. They rederived the Zehner-Schlunder equation (1970) and made some modifications to it. Comparison of predictions by this equation with 424 measured values shows the predictions to be accurate to within a ±30% relative error.

The Prediction of the Emissivity and Thermal Conductivity of Powder Beds

Synthesis-gas fermentations have typically been gas-to-liquid mass-transfer-limited due to low solubilities of the gaseous substrates. A potential method to enhance mass-transfer rates is to sparge with microbubble dispersions. Mass-transfer coefficients for microbubble dispersions were measured in a bubble column. Oxygen microbubbles were formed in a dilute Tween 20 solution using a spinning disk apparatus. Axial dispersion coefficients measured for the bubble column ranged from 1.5 to 7.2 cm2/s and were essentially independent of flow rate. A laser-diffraction technique was used to determine the interfacial area per unit gas volume, a. The mass-transfer coefficient, KL, was determined by fitting a plug-flow model to the experimental, steady-state, liquid-phase oxygen-concentration profile. The KL values ranged from 2.9 x 10(-5) to 2.2 x 10(-4) m/s. Volumetric mass-transfer coefficients, KLa, for microbubbles with an average initial diameter of 60 microns ranged from 200 to 1800 h-1. Enhancement of mass transfer using microbubbles was demonstrated for a synthesis-gas fermentation. Butyribacterium methylotrophicum was grown in a continuous, stirred-tank reactor using a tangential filter for total cell recycle. The fermentation KLa values were 14 h-1 for conventional gas sparging through a stainless steel frit and 91 h-1 for microbubble sparging. The Power number of the microbubble generator was determined to be 0.036. Using this value, an incremental power-to-volume ratio to produce microbubbles for a B. methylotrophicum fermentation was estimated to be 0.01 kW/m3 of fermentation capacity.

法昭若尾

Papers

Heat and mass transfer in packed beds

法昭 若尾

Papers

Heat and mass transfer in packed beds

法昭若尾