The present invention provides a process for making silica-filled rubber masterbatch using silica hydrophobated with a trimethoxy silane coupling agent that is soluble in an alcohol-water solution containing at least about 70 wt % water. One embodiment uses a mixture of trimethoxy silanes, one or more of which react with rubber to bond the silica to the rubber, and one or more of which do not react with rubber, but do hydrophobate the silica. Hydrophobated silica is mixed with latex polymer and incorporated into rubber during coagulation of the latex, which is preferably coagulated with calcium chloride. The present invention further provides a process for making the trimethoxy silane coupling agents. Preferred trimethoxy silane coupling agents include bis-(3-trimethoxysilylpropyl)-disulfide and bis-(3-trimethoxysilylpropyl)-tetrasulfide. Rubber products, particularly tires, compounded with the inventive silica masterbatch can be processed for a long time before scorching because the silica masterbatch provides a long scorch time.

Processes for making silane, hydrophobated silica, silica masterbatch and rubber products

An elastomer composite includes the coagulated product of a mixture of a particulate slurry and a latex blend comprising skim latex and at least one of field latex and latex concentrate.

An elastomer composite and method for producing it

Carbon blacks, such as rubber blacks, having a low PAH concentration are described. Furthermore, elastomeric or rubber compositions containing the carbon black of the present invention are further described, as well as methods of making carbon black having a low PAH concentration.

Carbon blacks having low PAH amounts and methods of making same

The present invention is to provide a production method of a natural rubber master batch including a step of mixing a natural rubber latex and an aqueous slurry having carbon black dispersed in water, wherein a mixing amount of the carbon black is from 10 to 100 parts by mass based on 100 parts by mass of a natural rubber component; and the carbon black is satisfied with the relationships expressed by (1) 120<CTAB adsorption specific surface area<160, (2) 50<24M4DBP<100, and (3) 75<toluene discoloration transmittance<95. Also, the present invention is to provide a natural rubber master batch obtained by the subject production method. Furthermore, the present invention is to provide a rubber composition using the foregoing natural rubber master batch and a tire using the subject rubber composition.

Method for producing natural rubber masterbatch, natural rubber masterbatch, rubber composition, and tire

An elastomer composite with silica-containing filler is described, along with methods to make the same. The advantages achieved with the elastomer composite and methods are further described.

Elastomer composite with silica-containing filler and methods to produce same

A process is provided for making a carbon-filled rubber having a uniform dispersion of nanometric-sized carbon black particles. Fluffy carbon black is received as a slurry in water and added to latex rubber before or during coagulation in an emulsion styrene butadiene rubber plant, or fluffy carbon black is similarly incorporated in rubber using a different type of rubber-manufacturing process. A uniform dispersion of smaller-than-usual carbon black particles in rubber is formed, which provides a black masterbatch rubber with superior mechanical and rheological properties. Ash and grit is removed from the fluffy carbon black slurry, which further improves the properties of the carbon-filled rubber by reducing defects in the rubber caused by the ash or grit.

Francisco Lopez-Serrano Ramos

Papers

Rubber and Carbon Black