Franco Magno

TL;DR: In this paper, the Nicholson's treatment for the evaluation of the heterogeneous standard rate constant k0 of electron transfer from cyclic voltammetric (CV) data is combined with the Klingler and Kochi method suitable to totally irreversible systems in order to use very large ΔEpx n values, where n is the number of electrons involved in a simple electron-transfer process O+n e−⇌R.

TL;DR: The paper summarizes critically the current approaches for the calculation of the limits of detection and quantification based on the calibration line and the explicit formulas relevant to the use of straight line and quadratic models are reported.

TL;DR: It was demonstrated that DA, a nonelectroactive compound, is ECL active and is responsible for the ECL behavior of H2A and the role of the OH- ion in the reaction mechanism of the two analytes appeared to be crucial.

TL;DR: PCA analysis indicated that nitrogen supplementation before fermentation determined a much clearer distinction between the VSC profiles of the two yeasts compared to nonsupplemented fermentations, which raises questions concerning the widespread use of DAP in the management of low YAN fermentations with respect to the formation of reductive characters in wine.

TL;DR: A new carbon electrode material, obtained by mixing single wall carbon nanotubes (SWNTs) with a mineral oil binder is studied in this paper, where the electron transfer rates of various redox couples under different pretreatment conditions are investigated.