F
Frank Rominger
Researcher at Heidelberg University
Publications - 966
Citations - 26305
Frank Rominger is an academic researcher from Heidelberg University. The author has contributed to research in topics: Catalysis & Chemistry. The author has an hindex of 73, co-authored 906 publications receiving 23004 citations. Previous affiliations of Frank Rominger include University of Düsseldorf.
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The Role of Gold Acetylides as a Selectivity Trigger and the Importance of gem-Diaurated Species in the Gold-Catalyzed Hydroarylating-Aromatization of Arene-Diynes
TL;DR: In this paper, the role of gold catalysts in catalyzing 1,2-dialkynylarenes was investigated, showing that gold plays a fascinating dual role serving to both catalyze the reaction and activate the substrate by Au-C-σ bond formation.
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Simple gold-catalyzed synthesis of benzofulvenes--gem-diaurated species as "instant dual-activation" precatalysts.
A. Stephen K. Hashmi,Ingo Braun,Pascal Nösel,Johannes Schädlich,Marcel Wieteck,Matthias Rudolph,Frank Rominger +6 more
TL;DR: The use of tertiary alkyl groups, the isolation of gem-diauratedspecies which prove to be ideal precatalysts for this type of transformation, the dynamics of the equilibrium involving these diaurated species, and the catalyst transfer in the context of a detailed mechanistic discussion are reported.
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Gold catalysis: isolation of vinylgold complexes derived from alkynes.
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Gold-Catalyzed C-H Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acylindoles.
TL;DR: The gold-catalyzed C-H annulation of anthranil derivatives with alkynes offers a facile, flexible, and atom-economical one-step route to unprotected 7-acylindoles and represents a versatile platform for the construction of diverse indolyl frameworks.
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Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis
TL;DR: In this article, organogold(I) phosphane complexes were prepared, their structure was investigated and their reactivity in reactions with Michael acceptors, sources of electrophilic halogens and protons were investigated.