Thermal energy storage technologies and systems for concentrating solar power plants

https://db.tamu.edu/publications/journal/DSDB_IJHMT_54_1064-1070_2011.pdf

Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy storage applications

The negative impact of human activities on the environment receives tremendous attention, especially on the increased global temperature. To combat climate change, clean and sustainable energy sources need to be rapidly developed. Solar energy technology is considered as one of the ideal candidates, which directly converts solar energy into electricity and heat without any greenhouse gas emissions. In both areas, high-performance cooling, heating and electricity generation is one of the vital needs. Modern nanotechnology can produce metallic or nonmetallic particles of nanometer dimensions which have unique mechanical, optical, electrical, magnetic, and thermal properties. Studies in this field indicate that exploiting nanofluid in solar systems, offers unique advantages over conventional fluids. In this paper, the applications of nanofluids on different types of solar collectors, photovoltaic systems and solar thermoelectrics are reviewed. Beside the wide range of energy conversion, the efforts done on the energy storage system (ESS) have been reviewed. In the field of economics, nanotech reduces manufacturing costs as a result of using a low temperature process.

A review on the applications of nanofluids in solar energy systems

The growing interest in energy applications of molten salts is justified by several of their properties. Their possibilities of usage as a coolant, heat transfer fluid or heat storage substrate, require thermo-hydrodynamic refined calculations. Many researchers are using simulation techniques, such as Computational Fluid Dynamics (CFD) for their projects or conceptual designs. The aim of this work is providing a review of basic properties (density, viscosity, thermal conductivity and heat capacity) of the most common and referred salt mixtures. After checking data, tabulated and graphical outputs are given in order to offer the most suitable available values to be used as input parameters for other calculations or simulations. The reviewed values show a general scattering in characterization, mainly in thermal properties. This disagreement suggests that, in several cases, new studies must be started (and even new measurement techniques should be developed) to obtain accurate values.

Molten salts database for energy applications

We have experimentally determined the solidus position of model lherzolite in the system CaO-MgO-Al2O3-SiO2-CO2 (CMAS.CO2) from 3 to 7 GPa by locating isobaric invariant points where liquid coexists with olivine, orthopyroxene, clinopyroxene, garnet and carbonate. The intersection of two subsolidus reactions at the solidus involving carbonate generates two invariant points, I1A and I2A, which mark the transition from CO2-bearing to dolomite-bearing and dolomite-bearing to magnesite-bearing lherzolite respectively. In CMAS.CO2, we find I1A at 2.6 GPa/1230 °C and I2A at 4.8 GPa/1320 °C. The variation of all phase compositions along the solidus has also been determined. In the pressure range investigated, solidus melts are carbonatitic with SiO2 contents of <6 wt%, CO2 contents of ˜45 wt%, and Ca/(Ca+Mg) ratios that range from 0.59 (3 GPa) to 0.45 (7 GPa); compositionally they resemble natural magnesiocarbonatites. Volcanic magnesiocarbonatites may well be an example of the eruption of such melts directly from their mantle source region as evidenced by their diatremic style of activity and lack of associated silicate magmas. Our data in the CMAS.CO2 system show that in a carbonate-bearing mantle, solidus and near-solidus melts will be CO2-rich and silica poor. The widespread evidence for the presence of CO2 in both the oceanic and continental upper mantle implies that such low degree SiO2-poor carbonatitic melts are common in the mantle, despite the rarity of carbonatites themselves at the Earth's surface.

G. J. Janz

Papers

Molten salts : data on single and multi-component salt systems