Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics such as work, heat and entropy production to the level of individual trajectories of well-defined non-equilibrium ensembles. It applies whenever a non-equilibrium process is still coupled to one (or several) heat bath(s) of constant temperature. Paradigmatic systems are single colloidal particles in time-dependent laser traps, polymers in external flow, enzymes and molecular motors in single molecule assays, small biochemical networks and thermoelectric devices involving single electron transport. For such systems, a first-law like energy balance can be identified along fluctuating trajectories. For a basic Markovian dynamics implemented either on the continuum level with Langevin equations or on a discrete set of states as a master equation, thermodynamic consistency imposes a local-detailed balance constraint on noise and rates, respectively. Various integral and detailed fluctuation theorems, which are derived here in a unifying approach from one master theorem, constrain the probability distributions for work, heat and entropy production depending on the nature of the system and the choice of non-equilibrium conditions. For non-equilibrium steady states, particularly strong results hold like a generalized fluctuation–dissipation theorem involving entropy production. Ramifications and applications of these concepts include optimal driving between specified states in finite time, the role of measurement-based feedback processes and the relation between dissipation and irreversibility. Efficiency and, in particular, efficiency at maximum power can be discussed systematically beyond the linear response regime for two classes of molecular machines, isothermal ones such as molecular motors, and heat engines such as thermoelectric devices, using a common framework based on a cycle decomposition of entropy production. (Some figures may appear in colour only in the online journal) This article was invited by Erwin Frey.

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Stochastic thermodynamics, fluctuation theorems and molecular machines

The relativistic fluid is a highly successful model used to describe the dynamics of many-particle, relativistic systems. It takes as input basic physics from microscopic scales and yields as output predictions of bulk, macroscopic motion. By inverting the process, an understanding of bulk features can lead to insight into physics on the microscopic scale. Relativistic fluids have been used to model systems as “small” as heavy ions in collisions, and as large as the Universe itself, with “intermediate” sized objects like neutron stars being considered along the way. The purpose of this review is to discuss the mathematical and theoretical physics underpinnings of the relativistic (multiple) fluid model. We focus on the variational principle approach championed by Brandon Carter and his collaborators, in which a crucial element is to distinguish the momenta that are conjugate to the particle number density currents. This approach differs from the “standard” text-book derivation of the equations of motion from the divergence of the stress-energy tensor in that one explicitly obtains the relativistic Euler equation as an “integrability” condition on the relativistic vorticity. We discuss the conservation laws and the equations of motion in detail, and provide a number of (in our opinion) interesting and relevant applications of the general theory.

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Relativistic fluid dynamics: physics for many different scales

Cardiovascular signals are largely analyzed using traditional time and frequency domain measures. However, such measures fail to account for important properties related to multiscale organization and non-equilibrium dynamics. The complementary role of conventional signal analysis methods and emerging multiscale techniques, is, therefore, an important frontier area of investigation. The key finding of this presentation is that two recently developed multiscale computational tools--multiscale entropy and multiscale time irreversibility--are able to extract information from cardiac interbeat interval time series not contained in traditional methods based on mean, variance or Fourier spectrum (two-point correlation) techniques. These new methods, with careful attention to their limitations, may be useful in diagnostics, risk stratification and detection of toxicity of cardiac drugs.

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Multiscale Analysis of Heart Rate Dynamics: Entropy and Time Irreversibility Measures

Phonon hydrodynamics and its applications in nanoscale heat transport

The present paper reports our attempt to search for a new universal framework in nonequilibrium physics. We propose a thermodynamic formalism that is expected to apply to a large class of nonequilibrium steady states including a heat conducting fluid, a sheared fluid, and an electrically conducting fluid. We call our theory steady state thermodynamics (SST) after Oono and Paniconi's original proposal. The construction of SST is based on a careful examination of how the basic notions in thermodynamics should be modified in nonequilibrium steady states. We define all thermodynamic quantities through operational procedures which can be (in principle) realized experimentally. Based on SST thus constructed, we make some nontrivial predictions, including an extension of Einstein's formula on density fluctuation, an extension of the minimum work principle, the existence of a new osmotic pressure of a purely nonequilibrium origin, and a shift of coexistence temperature. All these predictions may be checked experimentally to test SST for its quantitative validity.

Steady State Thermodynamics

Der vorliegende Band enthált sechs Beitrage, in denen punktuell und exemplarisch der Stand der Forschung beleuchtet wird. Ein Beitrag von Codling und Frasinski beschreibt in erster Linie Experimente zum noch wenig verstandenen Phânomen der dissoziativen Ionisation von Molekülen, bei dem diese in einem intensiven Laserfeld mehrere Elektronén verlieren und in Ionen mit hoher kinetischer Energie zerfallen. Ein wesentlicher Teil dieses Beitrags widmet sich einer von den Autoren entwickelten Auswertungstechnik, welche die Korrelationen zwischen den Fiugzeiten emittierter Ionen und Elektronén sichtbar macht. Es folgen drei Beitrage zur Théorie. Schmelcher und Cederbaum beschreiben Effekte starker statischer Felder, die nur dann zu verstehen sind, wenn die Nicht-Separation der Schwerpunktsbewegung im auBeren Magnetfeld korrekt beriicksichtigt wird. Dies fiihrt

G. Vojta

Papers

Extended Irreversible Thermodynamics