Review on transesterification of non-edible sources for biodiesel production with a focus on economic aspects, fuel properties and by-product applications

This present study focus on the process optimization and characteristic assessment of waste animal fat (WAF) biodiesel based on the influence of fatty acids characterized in it. WAFs were rendered ...

Influence of fatty acid composition on process optimization and characteristics assessment of biodiesel produced from waste animal fat

This present study deals with production of biodiesel from waste beef tallow using co-solvent based transesterification. Waste tallow was dry rendered from discarded fleshing and processing wastes; whose maximum fat content was estimated to be 48.35 ± 0.87%, collectively. Following this, biodiesel was produced from rendered tallow using methanol as primary solvent; and ethanol as co-solvent in presence of potassium hydroxide as base catalyst. Ideal range for reaction parameters were decided based on reaction parameters optimized for methanol based and ethanol based transesterification separately. Accordingly, the optimal reaction conditions for methanol-ethanol based transesterification are as follows: (1) oil to alcohol molar ratio: 1:6; (2) methanol to ethanol molar ratio: 3/3; (3) catalyst concentration: 0.55% KOH; (4) reaction temperature: 70 °C; (5) reaction time: 35 min and produced a maximum yield of 97.2 ± 1.08%. Apart from production optimization, the resultant biodiesel/tallow methyl ethyl ester (TMEE) was evaluated for its thermal & physicochemical properties as per ASTM D6751 standards. Interestingly, the fuel properties of TMEE were found to be superior than compared to tallow methyl esters and was accounted by presence of ethyl esters in them.

/pdf/process-optimization-of-biodiesel-production-from-waste-beef-2nlr4bae0r.pdf

Process optimization of biodiesel production from waste beef tallow using ethanol as co-solvent

Evaluation of various waste cooking oils for biodiesel production: A comprehensive analysis of feedstock.

This present study aims in understanding the influence of dominant fatty acid esters of waste animal fat biodiesel on its emission characteristics in CI engine. Biodiesel was produced from waste animal fat by means of base catalysed transesterification; and Ethyl oleate (40.21%), ethyl palmitate (25.36%) and ethyl stearate (16.87%) were characterized as dominant fatty acid esters using GC spectra. Test samples were prepared for these ester molecules based on their availability, in addition to biodiesel blend and plain diesel and were tested for their emission levels in single cylinder four stroke CI engine using flue gas analyser. High exhaust gas temperature was contributed by Ethyl oleate (1.15% lesser than biodiesel), as a result of low cetane number due to unsaturation and high viscosity. Likewise, the increased carbon chain length and unsaturation of ethyl oleate (2.55% lesser than biodiesel) resulted in high concentration of CO emission for biodiesel whereas high CO2 emission concentration was because of ester molecules with increased carbon chain length (stearate and Oleate esters). Reduced NOX emission for biodiesel was as a result of higher cetane number from ethyl stearate (CN=86.83) and ethyl palmitate (CN=86.55), which reduced its ignition delay thereby moderating the heat release rate. In addition, long carbon chained ester molecules (oleate and stearate esters) in biodiesel consumed more oxygen content for improving overall rate of combustion while increased HC emission was explained by unsaturation in biodiesel because of ethyl oleate (on average ,50 PPM).

/pdf/effect-of-dominant-fatty-acid-esters-on-emission-3u2th3rp07.pdf

Effect of Dominant Fatty Acid Esters on Emission Characteristics of Waste Animal Fat Biodiesel in CI Engine

Biodiesel is a long chain fatty acid alkyl ester molecule with robust characteristics suitable for both environment and as alternate energy resources. This paper aimed in summarizing the detailed literature study on biodiesel produced from waste animal fats discarded from leather tanneries and animal slaughter houses. This study concentrated on the extraction techniques, refining process, biodiesel production process along with its advantages and effect on engine. The fats had been proven to a viable feedstock when compared to vegetable oil and waste cooking oil in terms of productivity and economy. Various technical challenges involved in biodiesel production are food vs. fuel conflict over feedstock, auxiliary energy requirement for fat extraction and biodiesel production, Free Fatty Acid content, optimizing the reaction. Effects of biodiesel on engine application had also been discussed and will be providing wider scope of research for overcoming these short comes. This literature study affirmed that biodiesel produced from waste animal fat has a very good impact in reducing environmental pollution and moving a step ahead towards an effective sustainable development.

Gokul Raghavendr

Papers

Comprehensive study on biodiesel produced from waste animal fats-A review