Gregory J. Barbante

TL;DR: In this paper, the authors demonstrate the complete, rapid, and reversible switching between the emissions from two electrogenerated chemiluminescence (ECL) systems contained within the same solution, controlled by simple modification of the applied potential.

TL;DR: Using the distinct excitation and emission properties of concomitant electrochemiluminophores in conjunction with the inherent color selectivity of a conventional digital camera, a new strategy for multiplexed electrogenerated chemiluminescence detection is created, suitable for the development of low-cost, portable clinical diagnostic devices.

TL;DR: These luminescent redox systems create a range of new possibilities for multi-analyte ECL detection, assessment of interdependent electrochemical/spectroscopic properties, and color tuning in light-emitting devices.

TL;DR: The theoretical and experimental data together show that the best strategy for the design of efficient new blue-shifted electrochemiluminophores is to aim to stabilise the HOMO, while only moderately stabilising the LUMO, thereby increasing the energy gap but ensuring favourable thermodynamics and kinetics for the ECL reaction.

TL;DR: The emissions of the mixed annihilation ECL of metal complexes can be effectively predicted by estimations of reaction exergonicity.