Perylene Bisimide Dye Assemblies as Archetype Functional Supramolecular Materials

Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic nanographenes) are a highly versatile class of organic materials, applicable as functional chromophores and organic semiconductors. In this Review, we discuss the rich chemistry of large heteroaromatics, focusing on their synthesis, electronic properties, and applications in materials science. This Review summarizes the historical development and current state of the art in this rapidly expanding field of research, which has become one of the key exploration areas of modern heterocyclic chemistry.

Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications

This comprehensive review surveys developments over the past decade in the field of naphthalene diimides (NDIs). It explores their application toward: supramolecular chemistry; sensors; host–guest complexes for molecular switching devices, such as catenanes and rotaxanes; ion-channels by ligand gating; gelators for sensing aromatic systems; catalysis through anion−π interactions; and NDI intercalations with DNA for medicinal applications. We have also explored new designs, synthesis, and progress in the field of core-substituted naphthalene diimides (cNDIs), and their implications in areas such as artificial photosynthesis and solar cell technology. Also presented are some interesting synthetic routes and procedures that can be used toward further development of NDI-bearing compounds for future applications. Finally, we conclude with our views on NDI chemistry for future research endeavors, and we outline what we believe are the key obstacles that need to be overcome for NDIs to see real world applications.

Functional Naphthalene Diimides: Synthesis, Properties, and Applications

Fluorinated n-type conjugated polymers are used as efficient electron acceptor to demonstrate high-performance all-polymer solar cells. The exciton generation, dissociation, and charge-transporting properties of blend films are improved by using these fluorinated n-type polymers to result in enhanced photocurrent and suppressed charge recombination.

Fluoro‐Substituted n‐Type Conjugated Polymers for Additive‐Free All‐Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71%

Organic dyes and pigments constitute a large class of industrial products. The utilization of these compounds in the field of organic electronics is reviewed with particular emphasis on organic field-effect transistors. It is shown that for most major classes of industrial dyes and pigments, i.e., phthalocyanines, perylene and naphthalene diimides, diketopyrrolopyrroles, indigos and isoindigos, squaraines, and merocyanines, charge-carrier mobilities exceeding 1 cm(2) V(-1) s(-1) have been achieved. The most widely investigated molecules due to their n-channel operation are perylene and naphthalene diimides, for which even values close to 10 cm(2) V(-1) s(-1) have been demonstrated. The fact that all of these π-conjugated colorants contain polar substituents leading to strongly quadrupolar or even dipolar molecules suggests that indeed a much larger structural space shows promise for the design of organic semiconductor molecules than was considered in this field traditionally. In particular, because many of these dye and pigment chromophores demonstrate excellent thermal and (photo-)chemical stability in their original applications in dyeing and printing, and are accessible by straightforward synthetic protocols, they bear a particularly high potential for commercial applications in the area of organic electronics.

Organic Semiconductors based on Dyes and Color Pigments

Due to their high electron affi nities, chemical and thermal stabilities, π-conjugated molecules with imide/amide frameworks have received considerable attentions as promising candidates for high-performance optoelectronic materials, particularly for organic semiconductors with high carrier mobilities. The purpose of this Research News is to give an overview of recent advances in development of high performance imide/amide based organic semiconductors for fi eld-effect transistors. It covers naphthalene diimide-, perylene diimide- and amide-based conjugated molecules and polymers for organic semiconductors.

RESEARCH NEWS New Organic Semiconductors with Imide/Amide- Containing Molecular Systems

The invention discloses a conjugated micromolecule material based on bithiophene dipyrrole and derivatives thereof, and a preparation method and application thereof The molecular structure is disclosed as Formula I, wherein R1 and R2 independently represent C1-C50 alkyl group, C1-C50 alkoxy group, aralkyl group or heteroalkyl group; X1 and X2 independently represent carbon or nitrogen; and Ar1 and Ar2 independently represent an unsubstituted or substituted group: monocycloaryl group, bicycloaryl group, tricycloaryl group and above, monocyclo heteroaryl group, bicyclo heteroaryl group, tricyclo heteroaryl group and above, and 1-3 groups above connected by bonding (including single bond, double bond and triple bond) or condensing The micromolecule material has excellent current carrier transmission performance and solubility, and can be used in organic field-effect transistors and organic solar cells in the field of photoelectricity Formula I

Guanxin Zhang

Papers

RESEARCH NEWS New Organic Semiconductors with Imide/Amide- Containing Molecular Systems

Conjugated micromolecule material based on bithiophene dipyrrole and derivatives thereof, and preparation method and application thereof