Ever-growing global energy needs and environmental damage have motivated the pursuit of sustainable energy sources and storage technologies. As attractive energy storage technologies to integrate renewable resources and electric transportation, rechargeable batteries, including lead–acid, nickel–metal hydride, nickel–cadmium, and lithium-ion batteries, are undergoing unprecedented rapid development. However, the intrinsic toxicity of rechargeable batteries arising from their use of toxic materials is potentially environmentally hazardous. Additionally, the massive production of batteries consumes numerous resources, some of which are scarce. It is therefore essential to consider battery recycling when developing battery systems. Here, we provide a systematic overview of rechargeable battery recycling from a sustainable perspective. We present state-of-the-art fundamental research and industrial technologies related to battery recycling, with a special focus on lithium-ion battery recycling. We introduce the concept of sustainability through a discussion of the life-cycle assessment of battery recycling. Considering the forecasted trend of a massive number of retired power batteries from the forecasted surge in electric vehicles, their repurposing and reuse are considered from economic, technical, environmental, and market perspectives. New opportunities, challenges, and future prospects for battery recycling are then summarized. A reinterpreted 3R strategy entailing redesign, reuse, and recycling is recommended for the future development of battery recycling.

Toward sustainable and systematic recycling of spent rechargeable batteries

Recycling of lithium-ion batteries: Recent advances and perspectives

LiBs pose a very specific threat, given that they contain a high percentage of dangerous heavy metals. From the 4000 t of used lithium-ion batteries collected in 2005, 1100 t of heavy metals and more than 200 t of toxic electrolytes were generated. This is why a lot of attention has been paid to the development of the technology necessary to recover and recycle LiBs in order not only to protect the environment but also to conserve resources. The recovery of major spent cell components is beneficial both in terms of environmental protection and also for the provision of raw materials. The authors of this article carried out a state of the art on the technologies used in the recycling and regeneration of industrial lithium-ion batteries. The main objective of such technologies is to enable the recycling of valuable elements present in the batteries, such as cobalt, nickel and copper, in a way which is both profitable and environmentally friendly. All the technologies used in the manufacture of lithium-ion batteries are constantly changing makes subsequent changes to the research into recycling and recovery technologies necessary. This does not mean merely finding ways to recover the precious metals, but also to recover other materials which may harm the environment, in order to dispose of them appropriately. The discussion of this research clearly reflects that: • There are very few studies on the recovery of metals such as graphite, the electrolyte in spent LIBs, and it is our belief that more research is needed in this area. • The research into the application of microorganisms in the used lithium batteries is few and far between. • It is important to find ways to recover the precious metals and to recover other materials which may harm the environment, in order to dispose of them appropriately.

Processes and technologies for the recycling and recovery of spent lithium-ion batteries

A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries

As the consumption of lithium-ion batteries (LIBs) for the transportation and consumer electronic sectors continues to grow, so does the pile of battery waste, with no successful recycling model, as exists for the lead–acid battery. Here, we exhibit a method to recycle LIBs using deep eutectic solvents to extract valuable metals from various chemistries, including lithium cobalt (iii) oxide and lithium nickel manganese cobalt oxide. For the metal extraction from lithium cobalt (iii) oxide, leaching efficiencies of ≥90% were obtained for both cobalt and lithium. It was also found that other battery components, such as aluminium foil and polyvinylidene fluoride binder, can be recovered separately. Deep eutectic solvents could provide a green alternative to conventional methods of LIB recycling and reclaiming strategically important metals, which remain crucial to meet the demand of the exponentially increasing LIB production. The ever-increasing applications for Li-ion batteries in markets call for environmentally friendly and energy-efficient recycling technologies. Here the authors report using a deep eutectic solvent to extract valuable components of Li-ion batteries.

Hang Hu

Papers

Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries

Separation and recovery of metal values from leaching liquor of mixed-type of spent lithium-ion batteries