https://absimage.aps.org/image/MAR14/MWS_MAR14-2014-020819.pdf

Van der Waals heterostructures

Black phosphorus (BP), an emerging narrow direct band-gap two-dimensional (2D) layered material that can fill the gap between the semi-metallic graphene and the wide-bandgap transition metal dichalcogenides (TMDs), had been experimentally found to exhibit the saturation of optical absorption if under strong light illumination. By taking advantage of this saturable absorption property, we could fabricate a new type of optical saturable absorber (SA) based on mechanically exfoliated BPs, and further demonstrate the applications for ultra-fast laser photonics. Based on the balanced synchronous twin-detector measurement method, we have characterized the saturable absorption property of the fabricated BP-SAs at the telecommunication band. By incorporating the BP-based SAs device into the all-fiber Erbium-doped fiber laser cavities, we are able to obtain either the passive Q-switching (with maximum pulse energy of 94.3 nJ) or the passive mode-locking operation (with pulse duration down to 946 fs). Our results show that BP could also be developed as an effective SA for pulsed fiber or solid-state lasers.

Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and Mode-locking laser operation

The ultrafast relaxation and recombination dynamics of photogenerated electrons and holes in epitaxial graphene are studied using optical-pump Terahertz-probe spectroscopy. The conductivity in graphene at Terahertz frequencies depends on the carrier concentration as well as the carrier distribution in energy. Time-resolved studies of the conductivity can therefore be used to probe the dynamics associated with carrier intraband relaxation and interband recombination. We report the electron-hole recombination times in epitaxial graphene for the first time. Our results show that carrier cooling occurs on sub-picosecond time scales and that interband recombination times are carrier density dependent.

Ultrafast Optical-Pump Terahertz-Probe Spectroscopy of the Carrier Relaxation and Recombination Dynamics in Epitaxial Graphene

2D layered materials (2DLMs) are a subject of intense research for a wide variety of applications (e.g., electronics, photonics, and optoelectronics) due to their unique physical properties. Most recently, increasing research efforts on 2DLMs are projected toward the nonlinear optical properties of 2DLMs, which are not only fascinating from the fundamental science point of view but also intriguing for various potential applications. Here, the current state of the art in the field of nonlinear optics based on 2DLMs and their hybrid structures (e.g., mixed-dimensional heterostructures, plasmonic structures, and silicon/fiber integrated structures) is reviewed. Several potential perspectives and possible future research directions of these promising nanomaterials for nonlinear optics are also presented.

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Nonlinear Optics with 2D Layered Materials.

In this paper, we report 4 different saturable absorbers based on 4 transition metal dichalcogenides (MoS2, MoSe2, WS2, WSe2) and utilize them to Q-switch a ring-cavity fiber laser with identical cavity configuration. It is found that MoSe2 exhibits highest modulation depth with similar preparation process among four saturable absorbers. Q-switching operation performance is compared from the aspects of RF spectrum, optical spectrum, repetition rate and pulse duration. WS2 Q-switched fiber laser generates the most stable pulse trains compared to other 3 fiber lasers. These results demonstrate the feasibility of TMDs to Q-switch fiber laser effectively and provide a meaningful reference for further research in nonlinear fiber optics with these TMDs materials.

Q-switched fiber laser based on transition metal dichalcogenides MoS 2 , MoSe 2 , WS 2 , and WSe 2

In this paper, we demonstrated a passively mode-locked erbium-doped fiber (EDF) laser by incorporating a tungsten disulfide (WS2) film SA fabricated by pulsed laser deposition (PLD) method. The WS2 film was thickness-dependent, which had two different states: the bulk WS2 [faced to plasma plume] and tiny WS2 flakes [in the shadow of plasma plume]. This SA device demonstrated low insertion loss (IL) and high power tolerance ability. Interestingly, the SA device possessed different nonlinear absorption regimes related with the film states. By employing this new type of SA, we obtained stable fundamental mode-locking (FML) at pump power of 54 mW, and the generated soliton pulse had pulse duration of 675 fs and signal-to-noise ratio (SNR) of 65 dB. At the maximum pump power of 395 mW, we also obtained up to 1 GHz repetition rate of harmonic mode-locking (HML) with pulse duration of 452 fs and SNR of 48 dB. The experimental results show that WS2-PLD film can serve as a promising SA for ultrafast laser systems.

Microfiber-based WS 2 -film saturable absorber for ultra-fast photonics

A cell-type saturable absorber has been demonstrated by filling the single mode photonic crystal fiber (SMPCF) with tungsten disulfide (WS2) nanosheets. The modulation depth, saturable intensity and non-saturable loss of this SA are measured to be 3.53%, 159 MW/cm2 and 23.2%, respectively. Based on this SA, a passively mode-locked EDF laser has been achieved with pulse duration of 808 fs and repetition rate of 19.57 MHz and signal-noise-ratio (SNR) of 60.5 dB. Our results demonstrate that the cell-type WS2 nanosheets SA can serve as a good candidate for short-pulse mode locker.

/pdf/passively-mode-locked-fiber-laser-by-a-cell-type-ws2-4x525t8l3n.pdf

Passively mode-locked fiber laser by a cell-type WS2 nanosheets saturable absorber.

A novel saturable absorber (SA) was fabricated by coating the topological insulator (TI) film on microfiber using pulsed laser deposition (PLD) method. The TISA device had an insertion loss of ~1.25 dB, a saturable intensity of 26.7 MW/cm(2), a modulation depth of ~5.7%, and a nonsaturable loss of 20.5%. Upon employing this SA device, we established a passively mode-locked EDFL and achieved nearly free-chirped soliton pulse with 286 fs of pulse duration and >73 dB of signal to noise ratio (SNR). This result clearly evidences that the PLD is an effective scheme for practical SA device fabrication.

/pdf/a-practical-topological-insulator-saturable-absorber-for-4o2tmbl93n.pdf

A practical topological insulator saturable absorber for mode-locked fiber laser

By utilizing the pulsed laser deposition (PLD) method, we fabricated a kind of microfiber-based topological insulator (TI) saturable absorber (SA) which has inherent merits of effective and robust properties. We also proposed a newly explanation for the impact of nonlinear effect of SA on the harmonic mode-locking (HML) behavior. Upon employing on the SA, we achieved stable fundamental mode-locking (FML) at central wavelength of 1562.4 nm with pulse duration as short as 320 fs. By adjusting the intracavity polarization state at maximum pump power of 395 mW, we obtained stable femtosecond harmonic soliton pulse generation with repetition rate of 2.95 GHz and output power of 45.3 mW. Our results demonstrated that the microfiber-based TI PLD film SA is a promising device for practical multi-GHz ultrashort pulses generation.

A 2.95 GHz, femtosecond passive harmonic mode-locked fiber laser based on evanescent field interaction with topological insulator film

We first reported that the topological insulator (TI) nanosheets solution filled in photonic crystal fiber can operate as an effective saturable absorber (SA) with the merits of low-insertion loss ( $\sim 0.42$ dB), long interaction length (>10 cm), and high-power tolerance. This SA device exhibited a saturable intensity of 14.9 MW/ $\mathrm{cm}^{2}$ , modulation depth of 19.1%, and nonsaturable loss of 25% at 1060 nm. Upo employing, this device rendered us to establish an ytterbium-doped all-fiber laser oscillator, where stable evanescent wave mode-locking operation has been achieved. This letter provided a new way of utilizing the unique nonlinear optical property of TI.

Hao Chen

Papers

Microfiber-based WS 2 -film saturable absorber for ultra-fast photonics

Passively mode-locked fiber laser by a cell-type WS2 nanosheets saturable absorber.

A practical topological insulator saturable absorber for mode-locked fiber laser

A 2.95 GHz, femtosecond passive harmonic mode-locked fiber laser based on evanescent field interaction with topological insulator film

Topological Insulator Solution Filled in Photonic Crystal Fiber for Passive Mode-Locked Fiber Laser