Methods for forming hybrid nanowires are provided via forming a plurality of conductive nanowires extending radially from a surface of a flexible microwire; and then forming a thin film shell layer around the conductive nanowires. The conductive nanowires can include a metal oxide, and the thin film shell layer can include a transition metal oxide. Prior to forming the plurality of conductive nanowires, a catalyst coating layer can be formed on the surface of the carbon microfiber. Hybrid structures are also provided, which can include a flexible microwire defining a surface; a plurality of conductive nanowires extending radially from the surface of the flexible microfiber; and a thin film shell layer surrounding each conductive nanowire.

Flexible Zn2SnO4/MnO2 Core/Shell Nanocable - Carbon Microfiber Hybrid Composites for High Performance Supercapacitor Electrodes

A converter containing a NOx absorbing and reducing catalyst is disposed in the exhaust passage of an internal combustion engine. The upstream half portion (portion of the inlet side) of the substrate of the NOx absorbing and reducing catalyst in the converter carries the oxygen storage component that absorbs oxygen in the exhaust gas when the air-fuel ratio of the exhaust gas is lean and releases the absorbed oxygen when the air-fuel ratio of the exhaust gas flowing in is rich in addition to carrying the NOx absorbing and reducing catalyst. After NOx is absorbed by the NOx absorbing and reducing catalyst as a result of operating the engine at a lean air-fuel ratio, the engine is operated at a rich air-fuel ratio, so that NOx is released from the NOx absorbing and reducing catalyst and is purified by reduction. Here, oxygen is released from the oxygen storage component carried by the upstream half portion of the substrate and is reacted with the H 2 and CO components in the exhaust gas, so that the temperature of the NOx absorbing and reducing catalyst is raised within short periods of time due to the heat of reaction. Therefore, the catalyst exhibits increased activity and the NOx absorbing and reducing catalyst exhibits improved NOx purification capability.

Exhaust gas purification device for an internal combustion engine

A catalyst for purifying exhaust gases exhibits not only effective purifying characteristics even in a low temperature range such as immediately after an engine starts but also high exhaust gas purifying ability. In the catalyst for purifying exhaust gases of a first aspect of the invention, HC adsorbed at low temperature are released at high temperature and the released HC are purified by a catalyst metal. This catalyst for purifying exhaust gases has an excellent advantage in purifying HC at low temperature as well as excellent exhaust gas purifying ability.

Catalyst for purifying exhaust gases

The present invention is directed to a diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx). More particularly, the present invention is directed to a novel washcoat composition comprising two distinct washcoat layers containing two distinctly different ratios of Pt:Pd.

Pt-Pd Diesel Oxidation Catalyst with CO/HC Light-off and HC Storage Function

An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer facing the substrate and including a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope. Another exhaust gas-purifying catalyst includes a substrate, and a catalytic layer formed on the substrate using slurry containing a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope.

Exhaust gas purifying catalyst

In the exhaust gas purifying catalyst (3), palladium is contained as a catalytic component and cerium oxide and (Ce, Pr) compound oxide is contained as a promoter. Now, the weight ratio of cerium oxide to (Ce, Pr) compound oxide is set between 9/1 and 7/3, and the ratio of praseodymium to cerium in the (Ce, Pr) compound oxide is set between 3 mol % and 50 mol %. In this way, because in this exhaust gas purifying catalyst (3), palladium with high low-temperature activity is used for a catalytic component, the exhaust gas purifying performance at low temperature is improved. And because cerium oxide and (Ce, Pr) compound oxide improves catalytic activity of palladium at high temperature, the exhaust gas purifying performance at high temperature, in particular, NOx purifying performance, is improved.

Catalyst for cleaning exhaust gas

Method of forming a catalytic bonding layer by chemical vapor deposition (CVD) onto carrier structures including internal combustion engine exhaust system and catalytic converter components, in order to bond a catalyst layer thereto, thereby providing a structure wherein additionally the bonding layer can be energized to promote catalytic conversion-activating preheating of the catalyst. In an electromagnetic induction catalytic preheating system, a ceramic lattice or a metallic network can form the base structure of the catalytic converter, wherein at least the latter is encompassed by an electrical/thermal insulating layer; around either induction coiling is wrapped and secured by a thermally insulating material. Upon engine start, current is electromagnetically induced in the catalytic bonding layer or the metallic network through the induction coiling. Furthermore, the specific heat capacity of the bonding layer is low, and its specific resistance can be predetermined; thus in heating quickly and efficiently, in tandem the catalyst is heated. The catalytic preheating is also made efficient by the insulating properties of the insulating layers.

Exhaust gas catalytic purifier construction

An exhaust gas emission control catalyst includes an under catalyst layer containing at least one of barium and lanthanum and an over catalyst layer containing an agent for absorbing water in a gas, at least one of the under catalyst layer and over catalyst layer containing catalytic metal

Burned gas purifying catalyst

A catalyst carrier assembly for an automobile exhaust gas purifying device includes a smooth metal sheet and a pre-corrugated metal sheet wound alternately in a roll having a number of honeycomb convolutions. Each corrugation of the web-like pre-corrugated metal sheet is welded to the flat metal sheet at a plurality of points in the transverse direction during forming of the cylindrical roll. After forming the cylindrical roll, the cylindrical roll is heated so as to solder the web-like flat metal sheet and the web-like pre-corrugated metal sheet to each other at both of their end portions.

Catalyst for exhaust gas purification

There is provided an improved catalyst for purifying exhaust gases comprising a carrier carrying alumina, zirconium oxide and a noble metal catalyst The improvement resides in the fact that the carrier carries the alumina as a layer having dispersed therein the zirconium oxide particles, the zirconium oxide particles carrying said noble metal catalyst The dispersibility of the noble metal catalytic component is thereby improved and the sintering prevention effect on the noble metal catalytic component by the zirconium oxide is effectively exhibited Thus, the heat-proof property of the catalyst is improved and the cooperation between the noble metal catalytic component and alumina is effectively enhanced, improving longevity of the catalyst

Hiroshi Murakami

Papers

Catalyst for cleaning exhaust gas

Exhaust gas catalytic purifier construction

Burned gas purifying catalyst

Catalyst for exhaust gas purification

Catalyst for exhaust gas purification and method for producing the catalyst