Multiple sequential processes are conducted in a reaction chamber to form ultra high quality silicon-containing compound layers, including silicon nitride layers. In a preferred embodiment, a silicon layer is deposited on a substrate using trisilane as the silicon precursor. A silicon nitride layer is then formed by nitriding the silicon layer. By repeating these steps, a silicon nitride layer of a desired thickness is formed.

Method to form ultra high quality silicon-containing compound layers

A silicon nitride film is formed on a substrate in a reaction chamber by introducing trisilane and a reactive nitrogen species into the chamber in separate pulses. A carbon precursor gas is also flowed into the chamber during introduction of the trisilane and/or during introduction of the reactive nitrogen species, or in pulses separate from the trisilane and reactive nitrogen species pulses. The carbon is used as a dopant in the silicon nitride film and advantageously allows a high stress silicon nitride film to be formed.

High stress nitride film and method for formation thereof

Methods are provided for pulsed chemical vapor deposition (CVD) of complex nitrides, such as ternary metal nitrides. Pulses of metal halide precursors are separated from one another and nitrogen-containing precursor is provided during the metal halide precursor pulses as well as between the metal halide precursor pulses. Two different metal halide precursors can be provided in simultaneous pulses, alternatingly, or in a variety of sequences. The nitrogen-containing precursor, such as ammonia, can be provided in pulses simultaneously with the metal halide precursors and between the metal halide precursors, or continuously throughout the deposition. Temperatures can be kept between about 300° C. and about 700° C.

Deposition of complex nitride films

A method of forming a capacitor includes, a) providing a substrate; b) etching into the substrate to provide a depression in the substrate, the depression having a sidewall which is angled from vertical; c) providing a conformal layer of hemispherical grain polysilicon within the depression and over the angled sidewall, the layer of hemispherical grain polysilicon less than completely filling the depression; and d) ion implanting the hemispherical grain polysilicon layer with a conductivity enhancing impurity Preferred methods of providing the depression where the substrate comprises SiO 2 include a dry, plasma enhanced, anisotropic spacer etch utilizing reactant gases of CF 4 and CHF 3 provided to the substrate at a volumetric ratio of 1:1, and facet sputter etching

Method of forming a capacitor

Chemical vapor deposition processes utilize chemical precursors that allow for the deposition of thin films to be conducted at or near the mass transport limited regime. The processes have high deposition rates yet produce more uniform films, both compositionally and in thickness, than films prepared using conventional chemical precursors. In preferred embodiments, a higher order silane is employed to deposit thin films containing silicon that are useful in the semiconductor industry in various applications such as transistor gate electrodes.

Process for deposition of semiconductor films

The present invention provides a semiconductor device having a capacitor that is formed through: a first step of forming a polysilicon layer having a rough surface after a nonconductive layer is applied to a base substrate; a second step of etching back away the polysilicon layer to expose the nonconductive layer and thus remaining islandlike polysilicon layers; a third step of etching the nonconductive layer, using the remained polysilicon layers as an etching mask; a fourth step of etching the base substrate of the capacitor, using the nonconductive layer as a mask; a fifth step of forming a pattern of the base substrate of the capacitor after the removal of the remained nonconductive layer; a sixth step of forming an upper substrate of the capacitor after the formation of a dielectric film of the capacitor. According to this invention, the surface area of the capacitor electrode is remarkably enhanced such that the integrity of DRAMs is more improved.

Method for making a capacitor having an electrode surface with a plurality of trenches formed therein

A capacitor includes a first conductive layer having a plurality of cylindrical sections, dielectric film formed along the surface of the cylindrical sections and a second conductive substrate formed thereon. A semiconductor device is formed with the capacitor, has an increased capacitance and the integration of the semiconductor device is improved.

Method of making capacitor

A hemispherical grain (HSG) capacitor having HSGs on at least a part of the surface of capacitor lower electrodes, and a method of forming the same. In the capacitor, lower electrodes are formed of at least two amorphous silicon layers including an amorphous silicon layer doped with a high concentration of impurities and an amorphous silicon layer doped with a low concentration of impurities, and HSGs are formed, wherein the size of the hemispherical grains can be adjusted such that the size of HSGs formed on the inner surface of a U-shaped lower electrode or on the top of a stacked lower electrode is larger than that of HSGs formed on the outer surface of the U-shaped lower electrode or on the sidews of the stacked lower electrode. Thus, bridging between neighboring lower electrodes can be avoided by appropriately adjusting the size of HSGs, resulting in uniform capacitance wafer-to-wafer and within a wafer. The mechanical strength of the U-shaped lower electrode can also be enhanced.

Methods of forming HSG capacitors from nonuniformly doped amorphous silicon layers and HSG capacitors formed thereby

A silicon layer is formed on an integrated circuit substrate using silane and disilane thereby increasing a step coverage for the silicon layer, increasing a deposition rate for the silicon layer, reducing variability of the deposition rate, and reducing local crystallization of the silicon layer. More particularly, the step of forming the silicon layer can include forming a first silicon sublayer on the substrate using a first source gas including silane, and forming a second silicon sublayer on the first silicon sublayer using a second source gas different from the first source gas wherein the second source gas includes disilane. Alternately, the step of forming the silicon layer can include forming the silicon layer on the integrated circuit substrate using a source gas including a mixture of silane and disilane.

Dual source gas methods for forming integrated circuit capacitor electrodes

A method of forming a hemispherical grained silicon layer includes the step of forming a first amorphous silicon layer on an integrated circuit substrate by exposing the integrated circuit substrate to a first atmosphere including a silicon source gas and an anti-nucleation gas. A hemispherical grained silicon layer is formed on the amorphous silicon layer opposite the substrate. The anti-nucleation gas can be nitrogen oxide or oxygen.

Hyunbo Shin

Papers

Method for making a capacitor having an electrode surface with a plurality of trenches formed therein

Method of making capacitor

Methods of forming HSG capacitors from nonuniformly doped amorphous silicon layers and HSG capacitors formed thereby

Dual source gas methods for forming integrated circuit capacitor electrodes

Methods of forming hemispherical grained silicon layers including anti-nucleation gases