J
J. M. Alford
Researcher at Rice University
Publications - 10
Citations - 1024
J. M. Alford is an academic researcher from Rice University. The author has contributed to research in topics: Cluster (physics) & Chemisorption. The author has an hindex of 9, co-authored 10 publications receiving 1007 citations.
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Journal ArticleDOI
XPS probes of carbon-caged metals
J. H. Weaver,Y. Chai,G. H. Kroll,Changming Jin,T. R. Ohno,R. E. Haufler,Ting Guo,J. M. Alford,J. Conceicao,L. P. F. Chibante,A. Jain,G. Palmer,Richard E. Smalley +12 more
TL;DR: In this article, X-ray photoemission spectral probes of endohedral lanthanum-fullerene complexes, La@C n, show that the central La atom is in a formal charge state close to +3, and has been effectively protected from reaction with water an oxygen by the enclosing fullerene cage.
Journal ArticleDOI
Fourier transform ion cyclotron resonance studies of H2 chemisorption on niobium cluster cations
TL;DR: In this article, reaction rates and saturation values were determined for H2 dissociative chemisorption on positive niobium cluster ions in an FT-ICR apparatus.
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FT‐ICR probes of silicon cluster chemistry: The special behavior of Si+39
TL;DR: In this paper, the surface chemistry of isolated silicon cluster ions in the 7-65 atom size range was investigated and the results suggest the silicon clusters in this size range have well-defined structures which vary in ability to catalyze dissociative chemisorption at the surface.
Journal ArticleDOI
The electronic structure of Ca@C60
Lai-Sheng Wang,J. M. Alford,Y. Chai,M. Diener,Jing Zhang,S. M. McClure,Ting Guo,Gustavo E. Scuseria,Richard E. Smalley +8 more
TL;DR: In this article, the electron affinity of Ca@C60 was found to be 3.0 eV and the spectrum suggests that Ca donates its two 4s electrons to the C60 t1u LUMO.
Journal ArticleDOI
Ammonia chemisorption studies on silicon cluster ions
TL;DR: In this article, the Fourier transform ion cyclotron resonance apparatus was used to generate silicon clusters in the size range from 5 to 66 atoms and injected into the ion trap of a specially-designed Fourier transformer ion cycloton resonance apparatus, where the reaction behavior of many clusters clearly indicated that several structural isomers were present.