▪ Abstract The Re-Os isotope sytem, based on the long-lived β− transition of 187Re to 187Os, has matured to wide use in cosmochemistry and high-temperature geochemistry. The siderophilic/chalcophilic behavior of Re and Os is different from that of the elements that comprise most other long-lived radiogenic isotope systems. Magmatic iron meteorites (IIIAB, IIAB, IVA, and IVB) have Re-Os isochrons that indicate asteroidal core crystallization within the first 10–40 million years of Solar System evolution. Rocks from Earth's convecting mantle show generally chondritic Re/Os evolution throughout Earth history that is explained by the addition of highly siderophile elements to the mantle after core formation via late accretion. Oceanic basalts have Os-isotope systematics that improve the detailed geological interpretation of extant mantle components. Some portions of ancient subcontinental lithospheric mantle are severely depleted in Re and have correspondingly subchondritic 187Os/188Os, indicating long-term i...

THE Re-Os ISOTOPE SYSTEM IN COSMOCHEMISTRY AND HIGH-TEMPERATURE GEOCHEMISTRY

The Re-Os isotopic system in cosmochemistry and high temperature geochemistry

The origin of the fractionation of platinum-group elements in terrestrial magmas

The Luobusa ophiolite in the Indus—ladling Zjingbo suture of southern Tibet hosts the largest known chromite deposit in China. The podiform chromitites occur in a well-preserved mantle sequence consisting of harzburgite with abundant lenses of dunite. The harzburgites have relatively uniform bulk-rock compositions with mg-numbers [100Mg/(Mg + Fe) ] ranging from 89 to 91 and show flat, unfractionated, chondrite-normaliied platinum group element (PGE) patterns. Their accessory chromite varies widely in cr-number [100Cr/(Cr + Al)] (1866). These rocks are essentially residua left after extraction of mid-ocean ridge basalt (MORB)-type magmas. The podiform chromitites display nodular, massive, disseminated and banded textures and typically have dunite envelopes that grade into the surrounding harzburgite and diopsidic harzburgite with increasing pyroxene contents. They consist of relatively uniform chromite with high cv-numbers (74-82), have strongly fractionated, chondrite-normalized PGE patterns with enrichment in Os, Ir and Ru relative to Rh, Pt and Pt, and are believed to have formed from a boninitic magma produced by a second stage of melting. Dunites contain accessory chromite intermediate in composition between those of harzburgite and chromitite and are believed to be the products of reaction between new boninitic magmas and old MORB-type peridotites. The melt-rock reaction removed pyroxene from the peridotites and precipitated olivine, forming dunite envelopes around the chromitite pods. The melts thus became more boninitic in composition and chromite saturated, leading to precipitation of chromite alone. The interplay of melt—rock interaction, chromite fractionation and magma mixing should lead to many fluctuations in melt composition, producing both massive and disseminated chromitites and phase layering within individual podiform bodies observed in the Luobusa ophiolite.

Podiform Chromitites in the Luobusa Ophiolite (Southern Tibet): Implications for Melt-Rock Interaction and Chromite Segregation in the Upper Mantle

Abundance and distribution of gold, palladium and iridium in some spinel and garnet lherzolites: implications for the nature and origin of precious metal-rich intergranular components in the upper mantle

Platinum-group elements (PGE) are mined predominantly from deposits that have formed by the segregation of molten iron-nickel-copper sulfides from silicate magmas. The absolute concentrations of PGE in sulfides from different deposits vary over a range of five orders of magnitude, whereas those of other chalcophile elements vary by factors of only 2 to 100. However, the relative proportions of the different PGE in a given deposit are systematically related to the nature of the parent magma. The absolute and relative concentrations of PGE in magmatic sulfides are explained in terms of the degree of partial melting of mantle peridotite required to produce the parent magma and the processes of batch equilibration and fractional segregation of sulfides. The Republic of South Africa and the U.S.S.R. together possess more than 97 percent of the world PGE reserves, but significant undeveloped resources occur in North America. The Stillwater complex in Montana is perhaps the most important example.

https://science.sciencemag.org/content/sci/208/4451/1417.full.pdf

J. M. Duke

Papers

Platinum metals magmatic sulfide ores.