Showing papers by "Jacques E. Guerchais published in 1973"
TL;DR: In this article, the ligand 1,2-dithiole-3-thione and some derivatives substituted in the 4 and/or 5 positions yield complexes of the type FeX2L2(X = Cl, Br, or I), Iron(III) chloride is reduced, to give FeCl2L 2, and copper(II) salts yield copper(I) complexes, of the types CuXL2 (X = CL, Br or NO3) or CuXL3(X= Cl, BR, or ClO4).
Abstract: The ligand 1,2-dithiole-3-thione and some derivatives substituted in the 4- and/or 5-positions yield complexes of the type FeX2L2(X = Cl, Br, or I), Iron(III) chloride is reduced, to give FeCl2L2, and copper(II) salts yield copper(I) complexes of the types CuXL2(X = Cl, Br, or NO3) or CuXL3(X = Cl, Br, or ClO4). Physical studies, particularly electronic and Mossbauer spectra, show that the iron(II) compounds have pseudotetrahedral structures.
5 citations
TL;DR: In this paper, the ligand 1,2-dithiole-3-thione and some derivatives substituted in the 4 and/or 5 positions yield complexes of the type FeX2L2(X = Cl, Br, or I), Iron(III) chloride is reduced, to give FeCl2L 2, and copper(II) salts yield copper(I) complexes, of the types CuXL2 (X = CL, Br or NO3) or CuXL3(X= Cl, BR, or ClO4).
Abstract: The ligand 1,2-dithiole-3-thione and some derivatives substituted in the 4- and/or 5-positions yield complexes of the type FeX2L2(X = Cl, Br, or I), Iron(III) chloride is reduced, to give FeCl2L2, and copper(II) salts yield copper(I) complexes of the types CuXL2(X = Cl, Br, or NO3) or CuXL3(X = Cl, Br, or ClO4). Physical studies, particularly electronic and Mossbauer spectra, show that the iron(II) compounds have pseudotetrahedral structures.