Note: Times Cited: 875 Reference EPFL-ARTICLE-206025doi:10.1021/cr0501846View record in Web of Science URL: ://WOS:000249839900009 Record created on 2015-03-03, modified on 2017-05-12

Complex Hydrides for Hydrogen Storage

Gas hydrates have received considerable attention due to their important role in flow assurance for the oil and gas industry, their extensive natural occurrence on Earth and extraterrestrial planets, and their significant applications in sustainable technologies including but not limited to gas and energy storage, gas separation, and water desalination Given not only their inherent structural flexibility depending on the type of guest gas molecules and formation conditions, but also the synthetic effects of a wide range of chemical additives on their properties, these variabilities could be exploited to optimise the role of gas hydrates This includes increasing their industrial applications, understanding and utilising their role in Nature, identifying potential methods for safely extracting natural gases stored in naturally occurring hydrates within the Earth, and for developing green technologies This review summarizes the different properties of gas hydrates as well as their formation and dissociation kinetics and then reviews the fast-growing literature reporting their role and applications in the aforementioned fields, mainly concentrating on advances during the last decade Challenges, limitations, and future perspectives of each field are briefly discussed The overall objective of this review is to provide readers with an extensive overview of gas hydrates that we hope will stimulate further work on this riveting field

Gas hydrates in sustainable chemistry

The need for energy-efficient and environmentally friendly refrigeration, heat pumping, air conditioning, and thermal energy harvesting systems is currently more urgent than ever. Magnetocaloric energy conversion is among the best available alternatives for achieving these technological goals and has been the subject of substantial basic and applied research over the last two decades. The subject is strongly interdisciplinary, requiring proper understanding and efficient integration of knowledge in different specialized fields. This review article presents a historical and up-to-date account of the energy-related applications of magnetocaloric materials and information about their processing and magnetic fields, thermodynamics, heat transfer, and other relevant characteristics. The article also discusses the conceptual design of magnetocaloric refrigeration and power generation systems and some guidelines for future research in the field.

https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.201903741

Energy Applications of Magnetocaloric Materials

Hydrogen storage systems (HSSs), are the backbone of feasible hydrogen economy. To provide a reliable renewable energy system, safe, cost effective and compact HSS is due. Physical storage systems involve the compressed gas, liquid and cryo-compressed techniques while material based one involves adsorptive materials, metal hydrides and chemical storage materials. In this paper, the features of a variety of HSSs are impartially discussed. The technical comparative analysis of the different physical and material based types of HSSs illustrates the paradoxical inherent features, including gravimetric and volumetric storage densities and parameters associated with storage and release processes, among these systems. Accordingly, no ideal hydrogen storage technique can be considered the best-fit for all stationary and automotive applications. Therefore, not only a unique HSS solution can properly provide the needs, but a set of complementary HSS solutions which may offer the system designer several options. This set of options can be hardly interpretable in case of the unclear definition of the application needs which may be time variant. Inside this review, the critical insights and recommendations about suitable applications for storage systems are provided. Different standards and codes alongside the corresponding tests are demonstrated for the different storage technologies. Moreover, storage vessels research work is overviewed for the different hydrogen storage technologies. In addition, the failure behaviour, criteria and prediction models are investigated for composite vessels subjected to high pressures and extreme temperatures degrading their mechanical behaviour and failure resistance.

Hydrogen storage technologies for stationary and mobile applications: Review, analysis and perspectives

Ammonia is considered to be a potential medium for hydrogen storage, facilitating CO2-free energy systems in the future. Its high volumetric hydrogen density, low storage pressure and stability for long-term storage are among the beneficial characteristics of ammonia for hydrogen storage. Furthermore, ammonia is also considered safe due to its high auto ignition temperature, low condensation pressure and lower gas density than air. Ammonia can be produced from many different types of primary energy sources, including renewables, fossil fuels and surplus energy (especially surplus electricity from the grid). In the utilization site, the energy from ammonia can be harvested directly as fuel or initially decomposed to hydrogen for many options of hydrogen utilization. This review describes several potential technologies, in current conditions and in the future, for ammonia production, storage and utilization. Ammonia production includes the currently adopted Haber–Bosch, electrochemical and thermochemical cycle processes. Furthermore, in this study, the utilization of ammonia is focused mainly on the possible direct utilization of ammonia due to its higher total energy efficiency, covering the internal combustion engine, combustion for gas turbines and the direct ammonia fuel cell. Ammonia decomposition is also described, in order to give a glance at its progress and problems. Finally, challenges and recommendations are also given toward the further development of the utilization of ammonia for hydrogen storage.

Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization

Large-scale storage of hydrogen

Integration of water electrolysis for fossil-free steel production

Steelmaking is responsible for around 7% of the global emissions of carbon dioxide and new steelmaking processes are necessary to reach international climate targets. As a response to this, steelmaking processes based on the direct reduction of iron ore by hydrogen produced via water electrolysis powered by renewable electricity have been suggested. Here we present a novel variant of hydrogen-based steelmaking incorporating methanol as a hydrogen and carbon carrier together with high-temperature co-electrolysis of water and carbon dioxide and biomass oxy-fuel combustion. The energy and mass balances of the process are analyzed. It is found that this methanol-based direct reduction process may potentially offer a number of process-related advantages over a process based on pure hydrogen, featuring several process integration options. Notably, the electricity and total energy use of the steelmaking process could be reduced by up to 25% and 8% compared to a reference pure-hydrogen process, respectively. The amount of high-temperature (>200 °C) heat that must be supplied to the process could also be reduced by up to approximately 34%, although the demand for medium-temperature heat is substantially increased. Furthermore, the suggested process could allow for the production of high-quality direct reduced iron with appropriate carburization to alleviate downstream processing in an electric arc furnace, which is not the case for a process based on pure hydrogen.

Methanol as a carrier of hydrogen and carbon in fossil-free production of direct reduced iron

A Comparison of Two Hydrogen Storages in a Fossil Free Direct Reduced Iron Process

The set of 123-avoiding words with exactly r occurrences of each letter was recently enumerated by N. Shar and D. Zeilberger. This paper enumerates more complicated sets of pattern avoiding words, ...

/pdf/counting-words-avoiding-patterns-of-length-three-with-58c1vkwiev.pdf

Joakim Andersson

Papers

Large-scale storage of hydrogen

Integration of water electrolysis for fossil-free steel production

Methanol as a carrier of hydrogen and carbon in fossil-free production of direct reduced iron

A Comparison of Two Hydrogen Storages in a Fossil Free Direct Reduced Iron Process

Counting words avoiding patterns of length three with generating functions