A thermoplastic resin composition with enhanced elongation and good appearance comprising a compatible resin blend of a polyester sulfonate salt ionomer and a polyamide and an effective amount of at least one difunctional epoxy compound wherein the difunctional epoxy compound has at least one cyclohexane ring moiety and having two terminal epoxy functional groups, wherein at least one of the two terminal epoxy functional groups is a substituent on the at least one cyclohexane ring moiety; and optionally an effective amount of a catalyst compound or rubbery impact modifier.

Polyester molding composition

Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity and the Tg of the polyester provides for certain polyester properties. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.

Polyester Compositions Containing Cyclobutanediol Having a Certain Combination of Inherent Viscosity and Moderate Glass Transition Temperature and Articles Made Therefrom

Disclosed are oriented, shaped articles such as, for example, film, fibers, bottles, and tubes, with excellent strength, toughness, clarity, chemical resistance, and UV resistance. The articles can be prepared from cycloaliphatic polyesters and from compositions comprising cycloaliphatic polyesters and cycloaliphatic polyester elastomers. The articles may be oriented by stretching in at least one direction and have a modulus which results in a soft feel. Also disclosed are polyester compositions comprising cycloaliphatic polyesters and polyester elastomers.

Shaped articles from cycloaliphatic polyester compositions

Disclosed is a high Tg polyester/polymer blend composition suitable for melt processing into films. These films are suitable for liquid crystal displays as compensation or protective films.

Miscible high Tg polyester/polymer blend compositions and films formed therefrom

A three-dimensional model (26) and its support structure (28) are built by fused deposition modeling techniques, wherein a thermoplastic material containing silicone is used to form the support structure (28) and/or the model (26). The silicone acts as a release agent to facilitate removal of the support structure from the model after its completion. The thermoplastic material containing silicone exhibits good thermal stability, and resists build-up in the nozzle (24) of an extrusion head (12) or jetting head of a three-dimensional modeling apparatus (10).

Material and method for three-dimensional modeling

A blend of polycarbonates of dihydroxydiphenyl cycloalkanes and optionally 4,4'-isopropylidenediphenol with polyesters from terephthalic acid, isophthalic acid, 1,4-cyclohexanedimethanol and 2,2,4,4-tetramethyl-1,3-cyclobutanediol, having the advantage of being colorless and providing an unexpected amount of impact strength, hardness and heat resistance. The polymer blends are especially suitable for the manufacture of clear molded articles, fibers, sheeting, and film.

Clear polycarbonate and polyester blends

Disclosed are clear blends comprising: (A) from 1 to 99 percent by weight of a polycarbonate comprising a diol component comprising from 5 to 100 mol percent units of a diphenol or mixture of diphenols having the formula ##STR1## (B) from 1 to 99 percent by weight of a polyester comprising (a) a dicarboxylic acid component comprising from 80 to 100 mol percent 1,4-cyclohexane-dicarboxylic acid units; and from 0 to about 20 mol percent modifying dicarboxylic acid units having from 2 to 20 carbons, and (b) a glycol component comprising from 10 to 75 mol percent 2,2,4,4-tetramethyl-1,3-cyclobutanediol units, from 25 to 90 mol percent 1,4-cyclohexanedimethanol units, and from 0 to 10 mol percent modifying glycol units having 2 to 16 carbons, wherein the total units of said polyester is equal to 200 mol percent; wherein said blend is clear and the total weight percent of said polycarbonate (A) and said polyester (B) is equal to 100 weight percent.

Polycarbonate and polyester blends

Disclosed are clear blends comprising: (A) from 1 to 99 percent by weight of a polycarbonate comprising a diol component comprising from 90 to 100 mol percent 4,4'-isopropylidenediphenol units and from 0 to 10 mol percent modifying diol units having 2 to 16 carbons, wherein the total mol percent of diol units is equal to 100 mol percent; and (B) from 1 to 99 percent by weight of a polyester comprising (a) a dicarboxylic acid component comprising from 80 to 100 mol percent dicarboxylic acid units selected from the group consisting of terephthalic acid units, isophthalic acid units, and mixtures thereof; and from 0 to 20 mol percent modifying dicarboxylic acid units having about 2 to 20 carbons, wherein the total mol percent of dicarboxylic acid units is equal to 100 mol percent; and (b) a glycol component comprising from 30 to 99 mol percent 2,2,4,4-tetramethyl-1,3-cyclobutanediol units, from 1 to 70 mol percent ethylene glycol units, and from 0 to 10 mol percent modifying glycol units having from 3 to 16 carbons, wherein the total mol percent of glycol units is equal to 100 mol percent; wherein the total units of said polyester is equal to 200 mol percent; wherein said blend is clear and the total weight percent of said polycarbonate (A) and said polyester (B) is equal to 100 weight percent.

Blends of bisphenol a polycarbonate and polyesters

A blend of polycarbonates of dihydroxydiphenyl cycloalkanes and optionally 4,4'-isopropylidenediphenol with polyesters from terephthalic acid, isophthalic acid, ethylene glycol and 2,2,4,4-tetramethyl-1,3-cyclobutanediol, having the advantage of being colorless and providing an unexpected amount of impact strength, hardness and heat resistence. The polymer blends are especially suitable for the manufacture of clear molded articles, fibers, sheeting, and film.

Clear blends of polycarbonates and polyesters

The invention relates to a copolyester containing (a) a dicarboxylic acid component having from about 80 to 100 mole % terephthalic acid or the ester thereof; less than or equal to 20 mole % of an aromatic dicarboxylic acid having up to 20 carbon atoms or the ester thereof; and less than or equal to 10 mole % of an aliphatic dicarboxylic acid or an ester thereof having up to 16 carbon atoms; and (b) a glycol component having from about 25 to 85 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol, from about 15 to 75 mole % ethylene glycol; and less than or equal to 10 mole % of a diol having 3 to 16 carbon atoms, wherein the total mole % of the dicarboxylic acid component is 100 mole % and the total mole % of the glycol component is 100 mole %. The invention further relates to a process for preparing the above-identified copolyester. The invention further relates to a blend having from about 5 to 95 wt % of the above-identified copolyester; and from 5 to 95 wt % of a component comprising a flame retardant, a filler, a reinforcing agent, a polymer or a mixture thereof. The invention further relates to an article prepared from the above-identified copolyester and blend.

John C. Morris

Papers

Clear polycarbonate and polyester blends

Polycarbonate and polyester blends

Blends of bisphenol a polycarbonate and polyesters

Clear blends of polycarbonates and polyesters

Polyesters from terephthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol and ethylene glycol