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Showing papers by "John F. Nixon published in 1987"


Journal ArticleDOI
TL;DR: The first structurally characterised penta-and hexa-phosphorus analogues of ferrocene, bis-(η5-2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl)iron and (η 5-2.4,5,5 triphosphate-based butyl 1,3-diphosphacy clopentadiyl)-iron, are described in this article.
Abstract: The first structurally characterised penta- and hexa-phosphorus analogues of ferrocene, bis-(η5–2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl)iron and (η5-2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl)-(η5-2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl)iron, are described.

64 citations




Journal ArticleDOI
TL;DR: In this article, the structural features of tetrahedral alkyne and related P 2 compounds are discussed, in which the original tetrahedron cluster is intact and the structure of these complexes and related alkynes are discussed.

11 citations


Journal ArticleDOI
TL;DR: The remarkable hexa-rhodium compound [Rh2Cl2{Rh(η5-C5H5)(P2C2But2)}4] was obtained from the 1,3-diphosphacyclobutadiene complex as mentioned in this paper.
Abstract: The remarkable hexa-rhodium compound [Rh2Cl2{Rh(η5-C5H5)(P2C2But2)}4] is obtained from the 1,3-diphosphacyclobutadiene complex [Rh(η5-C5H5)(P2C2But2)] and [RhCl(C2H4)2]2.

10 citations


Journal ArticleDOI
TL;DR: An unusual carbonylation of a co-ordinated phospha-alkyne to give a phosphinidine was reported in this article, which was later used in the synthesis of a new protein.
Abstract: An unusual carbonylation of a co-ordinated phospha-alkyne to give a phosphinidine is reported.

7 citations


Journal ArticleDOI
TL;DR: The ligating unit PCRC(O)CRP (R = adamantyl) has been obtained from two phospha-alkynes RCP on treatment with [Rh2(CO)2(η5-C5Me5)2] as mentioned in this paper.
Abstract: The novel ligating unit PCRC(O)CRP (R = adamantyl) has been obtained from two phospha-alkynes RCP on treatment with [Rh2(CO)2(η5-C5Me5)2].

6 citations


Journal ArticleDOI
TL;DR: A variety of novel coordination complexes derived from phospha-alkynes and mono-and diphospha allenes were described in this article, where the coordination complexes were derived from a variety of coordination complexes.
Abstract: A variety of novel coordination complexes derived from phospha-alkynes, and mono- and diphospha-allenes will be described.

4 citations



Journal ArticleDOI
TL;DR: Different types of interactions of platinum, palladium and nickel complexes with phosphirene and phosphirane rings are discussed in this article, where the authors present different types of interaction between these compounds.
Abstract: Different types of interactions of platinum, palladium and nickel complexes with phosphirene and phosphirane rings are presented and discussed.