http://nathan.instras.com/ResearchProposalDB/doc-109.pdf

A review on polymer nanofibers by electrospinning and their applications in nanocomposites

Polymer/layered silicate nanocomposites: a review from preparation to processing

Recent years have seen a rapid growth of interest by the scientific and engineering communities in the thermal properties of materials. Heat removal has become a crucial issue for continuing progress in the electronic industry, and thermal conduction in low-dimensional structures has revealed truly intriguing features. Carbon allotropes and their derivatives occupy a unique place in terms of their ability to conduct heat. The room-temperature thermal conductivity of carbon materials span an extraordinary large range--of over five orders of magnitude--from the lowest in amorphous carbons to the highest in graphene and carbon nanotubes. Here, I review the thermal properties of carbon materials focusing on recent results for graphene, carbon nanotubes and nanostructured carbon materials with different degrees of disorder. Special attention is given to the unusual size dependence of heat conduction in two-dimensional crystals and, specifically, in graphene. I also describe the prospects of applications of graphene and carbon materials for thermal management of electronics.

Thermal properties of graphene and nanostructured carbon materials

Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy

Chemistry of Carbon Nanotubes

Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites

Dispersion of single wall carbon nanotubes by in situ polymerization under sonication

The recent surge in graphene research has stimulated interest in the investigation of various 2-dimensional (2D) nanomaterials. Among these materials, the 2D boron nitride (BN) nanostructures are in a unique position. This is because they are the isoelectric analogs to graphene structures and share very similar structural characteristics and many physical properties except for the large band gap. The main forms of the 2D BN nanostructures include nanosheets (BNNSs), nanoribbons (BNNRs), and nanomeshes (BNNMs). BNNRs are essentially BNNSs with narrow widths in which the edge effects become significant; BNNMs are also variations of BNNSs, which are supported on certain metal substrates where strong interactions and the lattice mismatch between the substrate and the nanosheet result in periodic shallow regions on the nanosheet surface. Recently, the hybrids of 2D BN nanostructures with graphene, in the form of either in-plane hybrids or inter-plane heterolayers, have also drawn much attention. In particular, the BNNS–graphene heterolayer architectures are finding important electronic applications as BNNSs may serve as excellent dielectric substrates or separation layers for graphene electronic devices. In this article, we first discuss the structural basics, spectroscopic signatures, and physical properties of the 2D BN nanostructures. Then, various top-down and bottom-up preparation methodologies are reviewed in detail. Several sections are dedicated to the preparation of BNNRs, BNNMs, and BNNS–graphene hybrids, respectively. Following some more discussions on the applications of these unique materials, the article is concluded with a summary and perspectives of this exciting new field.

Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene

Hexagonal boron nitride (h-BN), the isoelectric analogue of graphite, was functionalized using lipophilic and hydrophilic amine molecules. The functionalization induced the exfoliation of the layered structure of h-BN, resulting in few-layered and monolayered nanosheets soluble in common organic solvents and/or water. The soluble h-BN nanosheets were characterized using various solution-phase and solid-state techniques. For example, the optical extinction coefficients of the h-BN nanosheets in homogeneous dispersions were estimated to be much lower than those of graphene sheets, confirming their low-colored nature. Solution-phase NMR spectroscopy supported the mechanism that the amino groups of the functional molecules complex to the electron-deficient boron atoms on the h-BN nanosheet surfaces in terms of Lewis acid−base interactions. Results from other microscopic and spectroscopic characterizations of these functionalized two-dimensional nanomaterials are also presented, and the implications of the rep...

Soluble, Exfoliated Hexagonal Boron Nitride Nanosheets

Hexagonal boron nitride (h-BN) is traditionally considered to be insoluble in water. However, here we demonstrate that water is effective to exfoliate the layered h-BN structures with the assistance of bath sonication, forming “clean” aqueous dispersions of h-BN nanosheets without the use of surfactants or organic functionalization. Besides few-layered h-BN nanosheets, there was also evidence on the presence of monolayered nanosheet and nanoribbon species. Most nanosheets were of reduced lateral sizes, which was attributed to the cutting of parent h-BN sheets induced by the sonication-assisted hydrolysis (evidenced by the ammonia test and spectroscopy results). The hydrolysis effect also assisted in the exfoliation of h-BN nanosheets in addition to the solvent polarity effect. The h-BN nanosheets in such “clean” aqueous dispersions were demonstrated to be conveniently processed via solution methods with retained physical properties. The dispersed h-BN nanosheets in water also exhibited strong affinity tow...

John W. Connell

Papers

Dispersion of single wall carbon nanotubes by in situ polymerization under sonication

Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene

Soluble, Exfoliated Hexagonal Boron Nitride Nanosheets

Aqueous Dispersions of Few-Layered and Monolayered Hexagonal Boron Nitride Nanosheets from Sonication-Assisted Hydrolysis: Critical Role of Water

Carbon Nanosheets for Polymeric Nanocomposites with High Thermal Conductivity