The preparation, characterisation and applications of colloidal microgels

A relatively thin printed LED backlight device with an integral diffuser may be integrated into an interior trim component using a molding process, such as injection molding, compression molding and reaction injection molding. The display portion may be placed behind a textile surface or molded grille or may form a portion of the outer surface of the trim component to provide light to low light areas of the vehicle. Electronic circuitry and components may be printed on to the substrate of the device as part of an in-line continuous process at the molding station to allow low inventory and customization of each backlight device.

Integration of light emitting devices and printed electronics into vehicle trim components

An in-situ thickness monitoring/endpoint detection method and apparatus for chemical-mechanical polishing (CMP) of a dielectric layer on a top surface of a semiconductor wafer is disclosed. The apparatus comprises center and guard electrodes and associated electronic circuitry, including a high frequency, low voltage signal generating means, for converting a current which is inversely proportional to the dielectric layer thickness into a corresponding analog voltage. A position detection device triggers an analog-to-digital converter to convert the analog voltage into a digital signal while the wafer is located within a detection region as the wafer is being polished. A control means gathers the digital signals corresponding to the thickness data for processing and CMP device control.

In-situ endpoint detection method and apparatus for chemical-mechanical polishing using low amplitude input voltage

A method for measuring conductance of a sample using an eddy current probe with a sensing coil. The method includes N repetitions of measuring first and second voltage pairs including in-phase and quadrature components of an induced AC voltage in the sensing coil, calibrating the first signal based on the measured second signal at a different separation from the sample and reference material, determining a conductance function relating conductance with location along the selected curve, processing the calibrated first voltage pairs to generate a lift-off curve, determining an intersection voltage pair representing intersection of the lift-off curve with a selected curve, and determining the conductance of the sample from the intersection voltage pair and the conductance function.

In-situ metalization monitoring using eddy current measurements during the process for removing the film

Novel structural adhesive systems for metal-bonding applications. The adhesives, comprising a solution or dispersion of a polymeric material in a monomer copolymerizable therewith having incorporated therein certain phosphorus-containing compounds, are characterized by an unexpected ability of providing strong adhesion to untreated metal surfaces without adversely affecting adhesive performance, including resistance to deleterious environments. The environmental resistance of the herein described adhesives can be further improved by the addition of one or more polybasic lead salts, metal molybdates and metal phosphates.

Structural adhesive formulations

A radiation polymerizable protective coating composition or paint, coated articles bearing such a protective radiation polymerizable paint, which on a non-polymerizable solvent, pigment, initiator and particulate filler-free basis consists essentially of a binder solution of: (1) between about 90 and about 10 parts of a saturated, thermoplastic vinyl polymer prepared from at least about 85 weight percent of monofunctional vinyl monomers: (2) between about 10 and about 90 parts of vinyl solvent monomers for said vinyl polymer, at least about 10 weight percent, preferably at least about 30 weight percent, of said solvent monomers being selected from the group consisting of divinyl monomers, trivinyl monomers, tetravinyl monomers and mixtures thereof; and (3) between about 0.05 and about 1.0 parts per 100 parts of the total of said thermoplastic vinyl polymer and said vinyl solvent monomers of a mono- or diester of phosphoric acid bearing one or more sites of vinyl unsaturation. The composition exhibits excellent quality and good adhesion to a variety of substrates, in particular metals, including vapor deposited metals. Preferred articles bearing such a coating are prepared by: applying a base coat to a substrate and curing the same; vapor depositing a coating of a metal over the surface of the base coat; and applying to and curing on the surface of the deposited metal the radiation polymerizable topcoat, preferably with little or no pigment contained therein.

Radiation polymerizable coating composition containing an unsaturated phosphoric ester

A radiation polymerizable protective coating composition or paint, coated articles bearing such a protective radiation polymerizable paint, which on a non-polymerizable solvent, pigment, initiator and particulate filler-free basis consists essentially of a binder solution of: (1) between about 90 and about 10 parts of a thermoplastic vinyl polymer free of olefinic unsaturation and prepared from at least about 85 weight percent of monofunctional vinyl monomers: (2) between about 10 and about 90 parts of vinyl solvent monomers for said vinyl polymer, at least about 10 weight percent, preferably at least about 30 weight percent, of said solvent monomers being selected from the group consisting of divinyl monomers, trivinyl monomers, tetravinyl monomers and mixtures thereof; and (3) between about 0.05 and about 1.0 parts per 100 parts of the total of said thermoplastic vinyl polymer and said vinyl solvent monomers of a mono- or diester of phosphoric acid bearing one or more sites of vinyl unsaturation. The composition exhibits excellent quality and good adhesion to a variety of substrates, in particular metals, including vapor deposited metals. Preferred articles bearing such a coating are prepared by: applying a base coat to a substrate and curing the same; vapor depositing a coating of a metal over the surface of the base coat; and applying to and curing on the surface of the base coat; and applying to and curing on the surface of the deposited metal the radiation polymerizable topcoat, preferably with little or no pigment contained therein.

Plural coated article and process for making same

A radiation polymerizable protective coating composition or paint, coated articles bearing such a protective coating and processes for preparing such articles. The radiation polymerizable paint, on a non-polymerizable solvent, pigment, initiator and particulate filler-free basis consists essentially of a binder solution of: (1) an alpha-beta olefinically unsaturated organic resin containing between about .5 and about 5 units of olefinic unsaturation per 1,000 units of molecular weight; (2) a compound polymerizable with said resin upon exposure to ionizing radiation; and (3) between about 1.0 and about 15.0 parts per 100 parts of the total of said alpha-beta olefinically unsaturated resin and said compound polymerizable therewith of a triester of phosphoric acid bearing one or more sites of vinyl unsaturation. The composition exhibits excellent quality and good adhesion to a variety of substrates, in particular metals, including vapor deposited metals. Preferred articles bearing such a coating are prepared by: applying a base coat to a substrate and curing the same; vapor depositing a coating of a metal over the surface of the base coat; and applying to and curing on the surface of the deposited metal the radiation polymerizable topcoat, preferably with little or no pigment contained therein.

Protective coating composition

A method and apparatus for measuring the electrical conductivity of a liquid comprises an electrically insulating housing through which the liquid flows, and four electrodes inserted into the path of the liquid flowing through the housing The first and third electrodes are current electrodes and the second and fourth electrodes are voltage electrodes An AC current is injected into the first current electrode and exits at the second current electrode, with the resulting AC voltage across the voltage electrodes being measured The first current electrode is driven to maintain a constant value of AC voltage on the voltage electrodes while measuring the current flow in the second current electrode which is representative of the electrical conductivity of the liquid A DC bias voltage source is provided and is coupled to each of the electrodes by a resistor and a capacitor to prevent coating or plating of the electrodes The method and apparatus permit continuous monitoring of the absolute conductivity of a liquid

Continuous measurement of the absolute conductivity of a liquid

A low dosage radiation polymerizable protective and decorative coating composition or paint, coated articles bearing such a protective coating and processess for preparing such articles. The radiation polymerizable coating composition comprises an organic resin/monomer mixture of: (A) between about 97 and about 3 weight percent alpha-beta olefinically unsaturated organic resin containing between about 0.5 and about 5 vinyl unsaturation units per 1000 molecular weight of said resin, and (B) between about 3 and about 97 weight percent vinyl monomers polymerizable with said resin upon exposure to radiation, characterized in that said vinyl monomers include N-vinyl-2-pyrrolidone in an amount of from about 3 and up to about 10 weight percent based on the total weight of (A) and (B). The flexible coating exhibits excellent physical qualtities and good adhesion to a variety of substrates being particularly suitable for use on vinyl chloride fabric, wherein it is discoloration resistant after heat aging. Preferred articles bearing such a coating, which may comprise large amounts of pigment, are preferably cured by exposure to electron beam radiation.

Joseph C. Cassatta

Papers

Radiation polymerizable coating composition containing an unsaturated phosphoric ester

Plural coated article and process for making same

Protective coating composition

Continuous measurement of the absolute conductivity of a liquid

Discoloration resistant, flexible, radiation curable coating compositions