A method of controlling temperature during a pyrolysis reaction wherein the predominant pyrolysis reactions are endothermic. A fuel and oxidizer are combusted in a combustion zone to produce a hot gas stream at a superatmospheric pressure. The hot gas stream is then passed through a converging-diverging nozzle to accelerate the hot gas stream to a velocity of at least about mach 2. The reactant to be pyrolyzed is injected into the supersonic hot gas stream to produce a reaction mixture flowing at supersonic velocity and initiate the endothermic pyrolysis reactions. Substantially immediately thereafter the velocity of the reaction mixture is reduced over a predetermined reaction time to convert the kinetic energy of the reaction mixture to thermal energy in an amount sufficient to substantially offset the endothermic reactions taking place while maintaining supersonic flow. At the end of the predertermined reaction time the velocity of the reaction mixture is reduced to subsonic flow and the reaction quenched. The present invention is particularly adapted to the pyrolysis of methane to produce acetylene and ethylene by contacting the methane with hot gases resulting from the reaction of hydrogen with oxygen.

Method of controlling pyrolysis temperature

The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

Rapid starting methanol reactor system

Combined cycle power plants and related methods are disclosed here. In the plants, a mediating thermal energy storage unit (18) is used to store waste or residual thermal energy recovered from a heat engine employing a top thermodynamic cycle (10) of the combined cycle power plant, so that the stored residual thermal energy may be used as an energy source in a bottom thermodynamic cycle (11) of the power plant. In the combined cycle power plants described here, the heat engine employing a top cycle may comprise a Brayton cycle heat engine and the heat engine employing the bottom thermodynamic cycle may be a Rankine cycle heat engine.

Combined cycle power plant

Receivers for use in solar energy collector systems and solar-powered electrical energy generating plants are provided. The receivers (400) comprise a solar radiation absorbing core (414) that converts absorbed solar radiation to thermal energy. The core (414) comprises a refractory material to allow the receivers to operate continuously at high temperatures reached by absorbing concentrated solar radiation. The thermal energy so generated in the core may be stored in the receiver for a transitory period, or for a more extended period. Receivers (400) may comprise one or more fluid channels (415) in and/or around the core for conveying a working fluid to facilitate extraction of stored thermal energy from the core.

Integrated solar energy receiver-storage unit

A method for storing heat from a solar collector CSTC in Concentrating Solar Power plants and delivering the heat to the power plant PP when needed. The method uses a compressed gas such as carbon dioxide or air as a heat transfer medium in the collectors CSTC and transferring the heat by depositing it on a bed of heat-resistant solids and later, recovering the heat by a second circuit of the same compressed gas. The storage system HSS is designed to allow the heat to be recovered at a high efficiency with practically no reduction in temperature. Unlike liquid heat transfer media, our storage method itself can operate at very high temperatures, up to 3000° F., a capability which can lead to greater efficiency. Due to material constraints and cost considerations in the rest of the system the maximum temperature is presently limited to between 1700° F. and 2000° F. The method can be applied to all current solar collector designs. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.

Solar power plant and method and/or system of storing energy in a concentrated solar power plant

A thermal storage unit comprising a bed of particulate solid material, a liquid situated in heat-exchanging relation with said bed and cooperating with said bed to define a liquid-solid system containing a thermocline, and means for introducing liquid into and extracting liquid from said liquid-solid system.

Thermal energy storage unit

A quantity of aluminum is in heat exchange contact with a potassium loop and a steam/water loop. The potassium loop includes a solar energy collector and the solar-heated potassium melts the aluminum to store thermal energy as latent heat of fusion. The steam/water loop extracts steam at 1,000° F. as long as at least some of the aluminum is in the molten state. The steam/water loop includes a steam power turbogenerator unit as user; the quantity of aluminum should suffice to yield, upon resolidification, sufficient heat to satisfy the energy demand of the unit during night time.

Thermal buffer system

A method of producing high yields of olefins from hydrocarbon feedstocks which is particularly applicable to heavy hydrocarbons. In accordance with the present method, a stream of gaseous oxygen is introduced into a first reaction zone and a cocurrent flow of hydrogen is introduced about the periphery of the gaseous oxygen stream, the hydrogen being introduced at a temperature at which it will spontaneously react with the oxygen. The hydrogen and oxygen are introduced in amounts to provide a gas stream of reaction products having an average temperature within the range of from about 1,000° to 2,000° C. and which comprises a major amount of hydrogen and a minor amount of water vapor. The gas stream so produced is introduced into a second reaction zone and impinged upon a stream of hydrocarbon which is heated to a temperature in excess of its melting point but below the temperature at which any substantial coke or tar forms. The gas stream is introduced at a high velocity and in an amount to provide a flowing reaction mixture having a temperature within the range of from 800° to 1,800° C. The flowing mixture is maintained at that temperature for a time of from about 1 to 10 milliseconds to form olefins. Thereafter, the flowing mixture is rapidly quenched to arrest the reaction and the olefin products are recovered.

Method of producing olefins from hydrocarbons

A thermal storage system employing a fluid having a relatively high boiling point and capable of storage in separate phases, together with a substantial quantity of a chemically-compatible solid thermal storage medium.

Separated phase thermal storage system

A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000° C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

Joseph Friedman

Papers

Thermal energy storage unit

Thermal buffer system

Method of producing olefins from hydrocarbons

Separated phase thermal storage system

Hydrogenation of carbonaceous materials